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Abstract:

A new formulation is presented of the static relative permittivity or dielectric constant of water and steam, including supercooled and supercritical states. The range is from 238 K to 873 K, at pressures up to 1200 MPa. The formulation is based on the ITS-90 temperature scale. It correlates a selected set of data from a recently published collection of all experimental data. The set includes new data in the liquid water and the steam regions that have not been part of earlier correlations. The physical basis for the formulation is the so-called g-factor in the form proposed by Harris and Alder. An empirical 12-parameter form for the g-factor as a function of the independent variables temperature and density is used. For the conversion of experimental pressures to densities, the newest formulation of the equation of state of water on the ITS-90, prepared by Wagner and Pruss, has been used. All experimental data are compared with the formulation. The reliability of the new formulation is assessed in all subregions. Comparisons with previous formulations are presented. Auxiliary dielectric-constant formulations as functions of temperature are included for the saturated vapor and liquid states. The pressure and temperature derivatives of the dielectric constant and the Debye-Hückel limiting-law slopes are calculated, their reliability is estimated, and they are compared with experimentally derived values and with previous correlations. All equations are given in this paper, along with short tables. An implementation of this formulation for the dielectric constant is available on disk [A. H. Harvey, A. P. Peskin, and S. A. Klein, NIST/ASME Steam Properties, NIST Standard Reference Database 10, Version 2.1, Standard Reference Data Program, NIST, Gaithersburg, MD (1997)]. © 1997 American Institute of Physics and American Chemical Society.

Registro:

Documento: Artículo
Título:A formulation for the static permittivity of water and steam at temperatures from 238 K to 873 K at pressures up to 1200 MPa, including derivatives and Debye-Hückel coefficients
Autor:Fernández, D.P.; Goodwin, A.R.H.; Lemmon, E.W.; Levelt Sengers, J.M.H.; Williams, R.C.
Filiación:Phys. and Chem. Properties Division, Natl. Inst. of Std. and Technology, Gaithersburg, MD 20899, United States
Depto. Química de Reactores, Comn. Nac. de Energía Atomica, Avenue del Libertador 8250, 1429 Buenos Aires, Argentina
Ctr. for Appl. Thermodyn. Studies, University of Idaho, Moscow, ID 83844-1011, United States
Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon 2, 1428 Buenos Aires, Argentina
Phys. and Chem. Properties Division, Natl. Inst. of Std. and Technology, Boulder, CO 80303, United States
Palabras clave:Data correlation; Debye-Hückel coefficients; G-factor; ITS-90; Static dielectric constant; Static relative permittivity; Steam; Supercooled water; Supercritical steam; Water
Año:1997
Volumen:26
Número:4
Página de inicio:1125
Página de fin:1166
DOI: http://dx.doi.org/10.1063/1.555997
Título revista:Journal of Physical and Chemical Reference Data
Título revista abreviado:J. Phys. Chem. Ref. Data
ISSN:00472689
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00472689_v26_n4_p1125_Fernandez

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Citas:

---------- APA ----------
Fernández, D.P., Goodwin, A.R.H., Lemmon, E.W., Levelt Sengers, J.M.H. & Williams, R.C. (1997) . A formulation for the static permittivity of water and steam at temperatures from 238 K to 873 K at pressures up to 1200 MPa, including derivatives and Debye-Hückel coefficients. Journal of Physical and Chemical Reference Data, 26(4), 1125-1166.
http://dx.doi.org/10.1063/1.555997
---------- CHICAGO ----------
Fernández, D.P., Goodwin, A.R.H., Lemmon, E.W., Levelt Sengers, J.M.H., Williams, R.C. "A formulation for the static permittivity of water and steam at temperatures from 238 K to 873 K at pressures up to 1200 MPa, including derivatives and Debye-Hückel coefficients" . Journal of Physical and Chemical Reference Data 26, no. 4 (1997) : 1125-1166.
http://dx.doi.org/10.1063/1.555997
---------- MLA ----------
Fernández, D.P., Goodwin, A.R.H., Lemmon, E.W., Levelt Sengers, J.M.H., Williams, R.C. "A formulation for the static permittivity of water and steam at temperatures from 238 K to 873 K at pressures up to 1200 MPa, including derivatives and Debye-Hückel coefficients" . Journal of Physical and Chemical Reference Data, vol. 26, no. 4, 1997, pp. 1125-1166.
http://dx.doi.org/10.1063/1.555997
---------- VANCOUVER ----------
Fernández, D.P., Goodwin, A.R.H., Lemmon, E.W., Levelt Sengers, J.M.H., Williams, R.C. A formulation for the static permittivity of water and steam at temperatures from 238 K to 873 K at pressures up to 1200 MPa, including derivatives and Debye-Hückel coefficients. J. Phys. Chem. Ref. Data. 1997;26(4):1125-1166.
http://dx.doi.org/10.1063/1.555997