Artículo
Braslavsky, S.E.; Grotewold, J.; Lissi, E.A. "Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide" (1967) Journal of the Chemical Society B: Physical Organic:414-415
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Abstract:
The gas-phase photolysis of isopropyl iodide with light of wavelengths ≥3130 Å has been reinvestigated. In presence of mercury the only source of propene is the disproportionation of the isopropyl radicals. A value of 0·58 ± 0·04 was obtained for the combination- disproportionation ratio of the isopropyl radicals, in agreement with values given in the literature. This shows that alkyl iodides can be a useful source of free radicals.
Registro:
| Documento: | Artículo |
| Título: | Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide |
| Autor: | Braslavsky, S.E.; Grotewold, J.; Lissi, E.A. |
| Filiación: | Departamento di Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Buenos Aires, Argentina Universidad Técnica del Estado, Laboratorio Central de Química, Santiago, Chile |
| Año: | 1967 |
| Página de inicio: | 414 |
| Página de fin: | 415 |
| DOI: | http://dx.doi.org/10.1039/J29670000414 |
| Título revista: | Journal of the Chemical Society B: Physical Organic |
| ISSN: | 00456470 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00456470_v_n_p414_Braslavsky |
Citas:
---------- APA ----------
Braslavsky, S.E., Grotewold, J. & Lissi, E.A. (1967) . Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide. Journal of the Chemical Society B: Physical Organic, 414-415.http://dx.doi.org/10.1039/J29670000414
---------- CHICAGO ----------
Braslavsky, S.E., Grotewold, J., Lissi, E.A. "Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide" . Journal of the Chemical Society B: Physical Organic (1967) : 414-415.http://dx.doi.org/10.1039/J29670000414
---------- MLA ----------
Braslavsky, S.E., Grotewold, J., Lissi, E.A. "Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide" . Journal of the Chemical Society B: Physical Organic, 1967, pp. 414-415.http://dx.doi.org/10.1039/J29670000414
---------- VANCOUVER ----------
Braslavsky, S.E., Grotewold, J., Lissi, E.A. Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide. 1967:414-415.http://dx.doi.org/10.1039/J29670000414
