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Di Salvo, F.; Teixidor, F.; Viñas, C.; Giner Planas, J. "A distinct tetradentate N2O2-type ligand: (o-Carboranyl)bis(2-hydroxymethyl)pyridine" (2013) Zeitschrift fur Anorganische und Allgemeine Chemie. 639(7):1194-1198
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Abstract:

A new chiral racemic ligand (o-carboranyl)bis(2-hydroxymethyl)pyridine oCB(hmpH)2, that is composed of a central o-carborane unit where two arms radiate out of the cluster carbons each one containing a 2-pyridylmethylalcohol chelating arms, provides two potentially bidentate {NO} or one tetradentate {N2O2} binding pockets. An unprecedented octahedral CoII complex [CoCl2(anti- oCB(hmpH)2] was obtained under aerobic conditions and characterized by X-ray crystallography as well as IR and NMR spectroscopy. anti-oCB(hmpH) 2 acts as a tetradentate N2O2-ligand affording the complex as a racemic mixture of cis-α Δ-[CoCl2( RRanti-oCB(hmpH)2)] and Λ-[CoCl2( SSanti-oCB(hmpH)2)]. The new ligand oCB(hmpH)2 appears to be suitable for producing a variety of new chiral-at-metal complexes. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Registro:

Documento: Artículo
Título:A distinct tetradentate N2O2-type ligand: (o-Carboranyl)bis(2-hydroxymethyl)pyridine
Autor:Di Salvo, F.; Teixidor, F.; Viñas, C.; Giner Planas, J.
Filiación:Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus U.A.B, 08193 Bellaterra, Spain
Departamento de Química Inorgánica, Analítica, y Química Física, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellõn 2, C1428EHA Buenos Aires, Argentina
Palabras clave:Boron clusters; Carboranylalcohols; Chiral ligands; Cobalt; Self-assembly
Año:2013
Volumen:639
Número:7
Página de inicio:1194
Página de fin:1198
DOI: http://dx.doi.org/10.1002/zaac.201300116
Título revista:Zeitschrift fur Anorganische und Allgemeine Chemie
Título revista abreviado:Z. Anorg. Allg. Chem.
ISSN:00442313
CODEN:ZAACA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00442313_v639_n7_p1194_DiSalvo

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Citas:

---------- APA ----------
Di Salvo, F., Teixidor, F., Viñas, C. & Giner Planas, J. (2013) . A distinct tetradentate N2O2-type ligand: (o-Carboranyl)bis(2-hydroxymethyl)pyridine. Zeitschrift fur Anorganische und Allgemeine Chemie, 639(7), 1194-1198.
http://dx.doi.org/10.1002/zaac.201300116
---------- CHICAGO ----------
Di Salvo, F., Teixidor, F., Viñas, C., Giner Planas, J. "A distinct tetradentate N2O2-type ligand: (o-Carboranyl)bis(2-hydroxymethyl)pyridine" . Zeitschrift fur Anorganische und Allgemeine Chemie 639, no. 7 (2013) : 1194-1198.
http://dx.doi.org/10.1002/zaac.201300116
---------- MLA ----------
Di Salvo, F., Teixidor, F., Viñas, C., Giner Planas, J. "A distinct tetradentate N2O2-type ligand: (o-Carboranyl)bis(2-hydroxymethyl)pyridine" . Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 639, no. 7, 2013, pp. 1194-1198.
http://dx.doi.org/10.1002/zaac.201300116
---------- VANCOUVER ----------
Di Salvo, F., Teixidor, F., Viñas, C., Giner Planas, J. A distinct tetradentate N2O2-type ligand: (o-Carboranyl)bis(2-hydroxymethyl)pyridine. Z. Anorg. Allg. Chem. 2013;639(7):1194-1198.
http://dx.doi.org/10.1002/zaac.201300116