Artículo
Williams, P.A.M.; Ferrer, E.G.; Pasquevich, K.A.; Baran, E.J.; Chaia, Z.; Castellano, E.E.; Piro, O.E. "Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands " (2000) Zeitschrift fur Anorganische und Allgemeine Chemie. 626(12):2509-2514
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Abstract:
The crystal structure of the complexes [Cu(sac)2-(bzim)2(H2O)] (1) and [Cu(sac)2(bzim)(H2O)(EtOH)] · 2 EtOH (2) (sac = saccharinate anion; bzim = benzimidazole; EtOH = ethanol) was determined by single crystal X-ray diffractometry. Complex 1 crystallizes in the monoclinic C2/c space group with Z = 8 whereas complex 2 belongs to the triclinic P1̄ space group with Z = 2. Room temperature magnetic susceptibilities as well as electronic and IR spectra of both complexes were discussed. Their thermal behaviour was investigated by means of TG and DTA methods.
Registro:
| Documento: | Artículo |
| Título: | Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands |
| Autor: | Williams, P.A.M.; Ferrer, E.G.; Pasquevich, K.A.; Baran, E.J.; Chaia, Z.; Castellano, E.E.; Piro, O.E. |
| Filiación: | CEQUINOR, Facultad de Ciencias Exactas, UNLP, C. Correo 962, 1900-La Plata, Argentina CEQUINOR (CONICET, UNLP), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, La Plata, Argentina Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina Inst. de Fisica de Säo Carlos, Universidade de Säo Paulo, Säo Carlos, Brazil Depto. de Fisica and IFLP (CONICET), Faculdad de Ciencias Exactas, Universidad Nacional de La Plata, La Plata, Argentina |
| Palabras clave: | Benzimidazole; Copper(II); Crystal structures; Electronic spectra; IR-spectra; Saccharinate; Thermal behaviour |
| Año: | 2000 |
| Volumen: | 626 |
| Número: | 12 |
| Página de inicio: | 2509 |
| Página de fin: | 2514 |
| DOI: | http://dx.doi.org/10.1002/1521-3749(200012)626:12<2509::AID-ZAAC2509>3.0.CO;2-C |
| Título revista: | Zeitschrift fur Anorganische und Allgemeine Chemie |
| Título revista abreviado: | Z. Anorg. Allg. Chem. |
| ISSN: | 00442313 |
| CODEN: | ZAACA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00442313_v626_n12_p2509_Williams |
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Citas:
---------- APA ----------
Williams, P.A.M., Ferrer, E.G., Pasquevich, K.A., Baran, E.J., Chaia, Z., Castellano, E.E. & Piro, O.E. (2000) . Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands . Zeitschrift fur Anorganische und Allgemeine Chemie, 626(12), 2509-2514.http://dx.doi.org/10.1002/1521-3749(200012)626:12<2509::AID-ZAAC2509>3.0.CO;2-C
---------- CHICAGO ----------
Williams, P.A.M., Ferrer, E.G., Pasquevich, K.A., Baran, E.J., Chaia, Z., Castellano, E.E., et al. "Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands " . Zeitschrift fur Anorganische und Allgemeine Chemie 626, no. 12 (2000) : 2509-2514.http://dx.doi.org/10.1002/1521-3749(200012)626:12<2509::AID-ZAAC2509>3.0.CO;2-C
---------- MLA ----------
Williams, P.A.M., Ferrer, E.G., Pasquevich, K.A., Baran, E.J., Chaia, Z., Castellano, E.E., et al. "Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands " . Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 626, no. 12, 2000, pp. 2509-2514.http://dx.doi.org/10.1002/1521-3749(200012)626:12<2509::AID-ZAAC2509>3.0.CO;2-C
---------- VANCOUVER ----------
Williams, P.A.M., Ferrer, E.G., Pasquevich, K.A., Baran, E.J., Chaia, Z., Castellano, E.E., et al. Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands . Z. Anorg. Allg. Chem. 2000;626(12):2509-2514.http://dx.doi.org/10.1002/1521-3749(200012)626:12<2509::AID-ZAAC2509>3.0.CO;2-C
