Navegar

Colección

Datos Estadísticas

Artículo

Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

The thermal decomposition (TD) of basic iron nicotinate and isonicotinate proceeds in several stages: (a) dehydration to yield a hydroxocompound; (b) dehydration of hydroxide bridges, overlapping with water attack on the anion and release of H(nic) and H(isonic); (c) homolytic RC(O)O-Fe(III) bond breaking; (d) formation of metallic iron. Sodium salts decompose yielding Na2CO3 + C, that later evolves CO. The different types of chemical reactions involved in the TD of metal nicotinates and isonicotinates are compared. © 1989.

Registro:

Documento: Artículo
Título:The different pathways of the thermal decomposition of metal nicotinates and isonicotinates
Autor:Sileo, E.E.; Morando, P.J.; Blesa, M.A.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Argentina
Departamento Química de Reactores, Comisión Nacional de Energía Atómica, Avenida del Libertador 8250, 1429 Buenos Aires, Argentina
Año:1989
Volumen:152
Número:2
Página de inicio:299
Página de fin:306
DOI: http://dx.doi.org/10.1016/0040-6031(89)85399-7
Título revista:Thermochimica Acta
Título revista abreviado:Thermochim Acta
ISSN:00406031
CODEN:THACA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00406031_v152_n2_p299_Sileo

Referencias:

  • Sileo, Posse, Morando, Blesa, Herrera, della Vedova, Esteban, (1987) Polyhedron, 9, p. 1757
  • Sileo, Morando, della Vedova, Blesa, (1989) Thermochim. Acta, 138, p. 233
  • Morando, Piacquadio, Blesa, (1987) Thermochim. Acta, 117, p. 325
  • Bassi, Randhawa, Jamwal, (1983) Thermochim. Acta, 62, p. 209
  • Dollimore, Nicholson, 179. The thermal decomposition of oxalates. Part I. The variation of surface area with the temperature of treatment in air (1962) Journal of the Chemical Society (Resumed), p. 960
  • Dollimore, Nicholson, The thermal decomposition of oxalates. Part VI. The decomposition and surface properties of ferric oxalate (1966) Journal of the Chemical Society A: Inorganic, Physical, Theoretical, p. 281
  • Gallagher, Kurkjian, (1966) Inorg. Chem., 5, p. 214
  • Bassi, Randhawa, Jamwal, (1983) Thermochim. Acta, 65, p. 1
  • Galwey, 781. The thermal decomposition of basic ferric salts of benzoic acid and of phthalic acid (1965) Journal of the Chemical Society (Resumed), p. 4235
  • Galwey, The thermal decomposition of salts of mellitic acid. Part II. Ferric, cobalt, and nickel salts of mellitic acid (1966) Journal of the Chemical Society A: Inorganic, Physical, Theoretical, p. 87
  • Weast, Selvy, Hodgman, (1964) Handbook of Chemistry and Physics, p. 520. , The Chemical Rubber Co, Cleveland, OH
  • Carr, Galwey, The Kinetics and Mechanism of the Thermal Decomposition of Copper(II) Malonate (1986) Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 404, p. 127

Citas:

---------- APA ----------
Sileo, E.E., Morando, P.J. & Blesa, M.A. (1989) . The different pathways of the thermal decomposition of metal nicotinates and isonicotinates. Thermochimica Acta, 152(2), 299-306.
http://dx.doi.org/10.1016/0040-6031(89)85399-7
---------- CHICAGO ----------
Sileo, E.E., Morando, P.J., Blesa, M.A. "The different pathways of the thermal decomposition of metal nicotinates and isonicotinates" . Thermochimica Acta 152, no. 2 (1989) : 299-306.
http://dx.doi.org/10.1016/0040-6031(89)85399-7
---------- MLA ----------
Sileo, E.E., Morando, P.J., Blesa, M.A. "The different pathways of the thermal decomposition of metal nicotinates and isonicotinates" . Thermochimica Acta, vol. 152, no. 2, 1989, pp. 299-306.
http://dx.doi.org/10.1016/0040-6031(89)85399-7
---------- VANCOUVER ----------
Sileo, E.E., Morando, P.J., Blesa, M.A. The different pathways of the thermal decomposition of metal nicotinates and isonicotinates. Thermochim Acta. 1989;152(2):299-306.
http://dx.doi.org/10.1016/0040-6031(89)85399-7