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Abstract:

The thermal decomposition of copper(II) nicotinate and isonicotinate yields, in a sharp transition, metallic copper as the final solid residue along with the release of carbon dioxide and pyridine. In the case of the nicotinate, small amounts of nicotinic acid are also detected. The decomposition is started by homolytic RC(O)O-Cu bond scission, which is equivalent to electron transfer from RC(O)O- to Cu(II). © 1989.

Registro:

Documento: Artículo
Título:The thermal decomposition of copper(II) nicotinate and isonicotinate
Autor:Sileo, E.E.; Morando, P.J.; Della Vedova, C.O.; Blesa, M.A.
Filiación:Departamento de Quimica Inorgánica, Analitica y Quimica Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón II, Ciudad Universitaria, 1428 Buenos AiresArgentina
Departamento Quimica de Reactores, Cømision Nacional de Energia Atømica, Auenida del Libertador 8250, 1429 Buenos AiresArgentina
Programa QUINOR, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, Calle 47 y 115; (1900) La PlataArgentina
Año:1989
Volumen:138
Número:2
Página de inicio:233
Página de fin:239
DOI: http://dx.doi.org/10.1016/0040-6031(89)87259-4
Título revista:Thermochimica Acta
Título revista abreviado:Thermochim Acta
ISSN:00406031
CODEN:THACA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00406031_v138_n2_p233_Sileo

Referencias:

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  • E.E. Sileo, P.J. Morando, C.O. Della Vedova and M.A. Blesa, unpublished results

Citas:

---------- APA ----------
Sileo, E.E., Morando, P.J., Della Vedova, C.O. & Blesa, M.A. (1989) . The thermal decomposition of copper(II) nicotinate and isonicotinate. Thermochimica Acta, 138(2), 233-239.
http://dx.doi.org/10.1016/0040-6031(89)87259-4
---------- CHICAGO ----------
Sileo, E.E., Morando, P.J., Della Vedova, C.O., Blesa, M.A. "The thermal decomposition of copper(II) nicotinate and isonicotinate" . Thermochimica Acta 138, no. 2 (1989) : 233-239.
http://dx.doi.org/10.1016/0040-6031(89)87259-4
---------- MLA ----------
Sileo, E.E., Morando, P.J., Della Vedova, C.O., Blesa, M.A. "The thermal decomposition of copper(II) nicotinate and isonicotinate" . Thermochimica Acta, vol. 138, no. 2, 1989, pp. 233-239.
http://dx.doi.org/10.1016/0040-6031(89)87259-4
---------- VANCOUVER ----------
Sileo, E.E., Morando, P.J., Della Vedova, C.O., Blesa, M.A. The thermal decomposition of copper(II) nicotinate and isonicotinate. Thermochim Acta. 1989;138(2):233-239.
http://dx.doi.org/10.1016/0040-6031(89)87259-4