Artículo

El editor solo permite decargar el artículo en su versión post-print desde el repositorio. Por favor, si usted posee dicha versión, enviela a
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

The reaction of benzaldehyde with lithium metal was studied in two solvents and several temperatures as a model for more complex processes. Conditions were achieved to favor the adsorption of reactant on the metal surface, as wed as to slow down diffusion of the reactive species to solution: reaction within adsorbed species produces benzyl benzoate in high yield.

Registro:

Documento: Artículo
Título:Conversion of benzaldehyde into benzyl benzoate from the reaction with lithium metal in hexane
Autor:Nudelman, N.S.; Mendiara, S.
Filiación:Depto. de Quimica Organica, Facultad de Ciencias Exactas, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina
Depto. de Quimica, Facultad de Ciencias Exactas, Universidad de Mar del Plata, Mar del Plata, Argentina
Palabras clave:benzaldehyde; benzyl benzoate; adsorption; article; catalysis; drug synthesis; electron transport; in vitro study; methodology; model
Año:1997
Volumen:38
Número:13
Página de inicio:2245
Página de fin:2248
DOI: http://dx.doi.org/10.1016/S0040-4039(97)00334-1
Título revista:Tetrahedron Letters
Título revista abreviado:TETRAHEDRON LETT.
ISSN:00404039
CODEN:TELEA
CAS:benzaldehyde, 100-52-7; benzyl benzoate, 120-51-4, 8022-66-0
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v38_n13_p2245_Nudelman

Referencias:

  • Adamson, A.W., (1990) Physical Chemistry of Surfaces, , Wiley & Sons, New York
  • Sinfelt, J.H., (1987) Acc. Chem. Res., 20, p. 134
  • Stockwell, D.M., Bennett, C.O., (1988) J. Catal., 110, p. 354
  • Stockwell, D.M., Chung, J.S., Bennett, C.O., (1988) J. Catal., 122, p. 135
  • Baetzold, R.C., Monnier, J.R., (1986) J. Phys. Chem., 90, p. 2944
  • Nudelman, N.S., Carbonylation of main-group organometallic compounds (1989) The Chemistry of Double Bonded Functional Groups, , Patai, S. and Rappoport, Z. eds., ch. 13, Wiley, Chichester and references therein
  • Nudelman, N.S., Lewkowicz, E.S., Furlong, J.P.J., (1993) J. Org. Chem., 58, p. 1847
  • Nudelman, N.S., Lewkowicz, E.S., Perez, D.R., (1990) Synthesis, p. 917
  • Nudelman, N.S., Doctorovich, F., (1994) Tetrahedron, 50, p. 4651
  • Baerns, M., Ross, J.R.H., Van Der Wiele, K., (1989) Methane Activation, Catalysis Today, p. 4
  • Nudelman, N.S., Mendiara, S., (1996) J. Phys. Org. Chem., , in press
  • Stapp, P.R., (1973) J. Org. Chem., 38, p. 1433
  • Larock, R.C., (1989) Comprehensive Organic Transformations, p. 840. , VCH, New York
  • Fox, M.A., (1992) Chem. Rev., 92, p. 365. , and refs. therein
  • Masnovi, J., Maticic, J., (1988) J. Am. Chem. Soc., 110, p. 5189
  • Saito, Y., Ikehera, H., Kasatani, R., Watanabe, M., Matsuura, T., (1986) J. Am. Chem. Soc., 108, p. 5190
  • Masnovi, J., Samsel, E.G., Bullok, R.M., (1989) J. Chem. Soc. Chem Comm, p. 1044
  • Ashby, E.C., Coleman, D., Gamasa, M., (1987) J. Org. Chem., 52, p. 4079
  • Shriver, D.F., (1989) The Manipulation of Air-Sensitive Compounds, , Wiley, N. Y

Citas:

---------- APA ----------
Nudelman, N.S. & Mendiara, S. (1997) . Conversion of benzaldehyde into benzyl benzoate from the reaction with lithium metal in hexane. Tetrahedron Letters, 38(13), 2245-2248.
http://dx.doi.org/10.1016/S0040-4039(97)00334-1
---------- CHICAGO ----------
Nudelman, N.S., Mendiara, S. "Conversion of benzaldehyde into benzyl benzoate from the reaction with lithium metal in hexane" . Tetrahedron Letters 38, no. 13 (1997) : 2245-2248.
http://dx.doi.org/10.1016/S0040-4039(97)00334-1
---------- MLA ----------
Nudelman, N.S., Mendiara, S. "Conversion of benzaldehyde into benzyl benzoate from the reaction with lithium metal in hexane" . Tetrahedron Letters, vol. 38, no. 13, 1997, pp. 2245-2248.
http://dx.doi.org/10.1016/S0040-4039(97)00334-1
---------- VANCOUVER ----------
Nudelman, N.S., Mendiara, S. Conversion of benzaldehyde into benzyl benzoate from the reaction with lithium metal in hexane. TETRAHEDRON LETT. 1997;38(13):2245-2248.
http://dx.doi.org/10.1016/S0040-4039(97)00334-1