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Abstract:

The reaction of [Ru(bpy)2(NO)Cl]2+ with 2,2,2-trifluoroethylamine produced [Ru(bpy)2(NO)Cl]+ by electron transfer and a number of organic compounds formed via nucleophilic substitution of the intermediate 2,2,2-trifluoroethyldiazonium ion (free or coordinated). Density functional theory computed results suggest that stabilization of the trifluoroethyldiazonium ion by complexation is much larger than the one corresponding to the butyl ion, in agreement with the fact that no rearrangement products derived from CF3CH2+ were observed. © 2002 Elsevier Science Ltd. All rights reserved.

Registro:

Documento: Artículo
Título:Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+
Autor:Di Salvo, F.; Crespo, A.; Estrin, D.A.; Doctorovich, F.
Filiación:Departamento de Quı́mica Inorgánica, Analı́tica y Quı́mica Fı́sica/INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, CEHA Buenos Aires, Ciudad Universitaria, Pabellón II, piso 3 (1428), Argentina
Palabras clave:2,2,2-trifluoroethylamine; Complex; Density functional theory; Electron transfer; n-butylamine; Nitrosyl; Ruthenium; 2,2,2 trifluoroethylamine; butylamine; ethylamine; ruthenium complex; unclassified drug; article; calculation; chemical reaction; complex formation; electron transport; molecular stability; priority journal; reaction analysis; solvation; theory
Año:2002
Volumen:58
Número:21
Página de inicio:4237
Página de fin:4244
DOI: http://dx.doi.org/10.1016/S0040-4020(02)00382-4
Título revista:Tetrahedron
Título revista abreviado:Tetrahedron
ISSN:00404020
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404020_v58_n21_p4237_DiSalvo

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Citas:

---------- APA ----------
Di Salvo, F., Crespo, A., Estrin, D.A. & Doctorovich, F. (2002) . Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+. Tetrahedron, 58(21), 4237-4244.
http://dx.doi.org/10.1016/S0040-4020(02)00382-4
---------- CHICAGO ----------
Di Salvo, F., Crespo, A., Estrin, D.A., Doctorovich, F. "Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+" . Tetrahedron 58, no. 21 (2002) : 4237-4244.
http://dx.doi.org/10.1016/S0040-4020(02)00382-4
---------- MLA ----------
Di Salvo, F., Crespo, A., Estrin, D.A., Doctorovich, F. "Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+" . Tetrahedron, vol. 58, no. 21, 2002, pp. 4237-4244.
http://dx.doi.org/10.1016/S0040-4020(02)00382-4
---------- VANCOUVER ----------
Di Salvo, F., Crespo, A., Estrin, D.A., Doctorovich, F. Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+. Tetrahedron. 2002;58(21):4237-4244.
http://dx.doi.org/10.1016/S0040-4020(02)00382-4