Abstract:
Reported here is a boron process equivalent to stereoselective olefin reduction and concomitant protecting group cleavage. © 1995, Taylor & Francis Group, LLC. All rights reserved.
Registro:
Documento: |
Artículo
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Título: | Reduction of a Δ4-Steroid with Diborane |
Autor: | D'Alessandro, C.; Giacopello, S.; Seldes, A.M.; Deluca, M.E. |
Filiación: | Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, (1428), Buenos Aires, Argentina
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Palabras clave: | 5β-steroids; boron rearrangement; molecular mechanics; synthesis; cholesterol derivative; article; drug synthesis; methodology; nuclear magnetic resonance; reduction; stereochemistry |
Año: | 1995
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Volumen: | 25
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Número: | 18
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Página de inicio: | 2703
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Página de fin: | 2708
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DOI: |
http://dx.doi.org/10.1080/00397919508011818 |
Título revista: | Synthetic Communications
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Título revista abreviado: | Synth. Commun.
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ISSN: | 00397911
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00397911_v25_n18_p2703_DAlessandro |
Referencias:
- Snyder, B.W., Winneker, R.C., Batzold, F.H., (1989) J. Steroid Biochem., 33, p. 1127
- Christiansen, R.G., Bell, M.R., D'Ambra, T.E., Mallamo, J.P., Herrmann, J.L., Ackerman, J.H., Opalka, C.J., Schane, H.P., (1990) J. Med. Chem., 33 (8), p. 2094
- Blunt, J.W., Stothers, J.B., (1977) Org. Magn. Reson., 9 (8), p. 439
- Dart, M.C., Henbest, H.B., (1960) J. Chem. Soc, p. 3563
- Fried, J., Edwards, J.A., (1972), 1. , Eds.; Van Nostrand Reinhold: New York, Chapter 3; Ravasio, N., Rossi, M., (1991) J. Org. Chem., 56, p. 4329
- Allinger, N.L., (1977), The force field used in PCMODEL is called MMX and is derived from the MM2(QCPE-395) force field of, with the pi-VESCF routines taken from MMP1(QCPE-318), also by N.L. Allinger; Bryson, T.A., Akers, J.A., Ergle, J.D., (1991) Synlett, p. 499
Citas:
---------- APA ----------
D'Alessandro, C., Giacopello, S., Seldes, A.M. & Deluca, M.E.
(1995)
. Reduction of a Δ4-Steroid with Diborane. Synthetic Communications, 25(18), 2703-2708.
http://dx.doi.org/10.1080/00397919508011818---------- CHICAGO ----------
D'Alessandro, C., Giacopello, S., Seldes, A.M., Deluca, M.E.
"Reduction of a Δ4-Steroid with Diborane"
. Synthetic Communications 25, no. 18
(1995) : 2703-2708.
http://dx.doi.org/10.1080/00397919508011818---------- MLA ----------
D'Alessandro, C., Giacopello, S., Seldes, A.M., Deluca, M.E.
"Reduction of a Δ4-Steroid with Diborane"
. Synthetic Communications, vol. 25, no. 18, 1995, pp. 2703-2708.
http://dx.doi.org/10.1080/00397919508011818---------- VANCOUVER ----------
D'Alessandro, C., Giacopello, S., Seldes, A.M., Deluca, M.E. Reduction of a Δ4-Steroid with Diborane. Synth. Commun. 1995;25(18):2703-2708.
http://dx.doi.org/10.1080/00397919508011818