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Abstract:

1,2-Dicyano-4,5-di[(N,N-dimethylaminocarbonyl)methoxy]benzene (5) was synthesized in 80% yield from the corresponding 1,2-dibromo derivative 4. Octa(peripheral-amide)substituted zinc(II) phthalocyanine 6 was obtained from 5 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene. Phthalocyanine 7 was prepared via reduction of 6 with diborane. Treatment of 7 with methyl iodide afforded cationic dye 8. © Georg Thieme Verlag Stuttgart.

Registro:

Documento: Artículo
Título:Reduction of an amido zinc(II) phthalocyanine by diborane
Autor:Strassert, C.A.; Dicelio, L.E.; Awruch, J.
Filiación:Departamento de Química Orgánica, Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Junín 956, 1113 Buenos Aires, Argentina
Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina
Palabras clave:Nucleophilic aromatic substitution; Phthalocyanines; Reduction; Dyes; Positive ions; Nucleophilic aromatic substitution; Phthalocyanines; Reduction; Semiconducting zinc compounds; 1,2 dicyano 4,5 di[(n,n dimethylaminocarbonyl)methoxy]benzene; 1,8 diazabicyclo[5.4.0]undec 7 ene; 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminocarbonyl)methoxy]phthalocyaninatozinc(ii); 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminoethoxy)]phthalocyaninatozinc(ii); 2,3,9,10,16,17,23,24 octakis[(n,n,n triethylammonium)ethoxy]phthalocyaninatozinc(ii)octaiodide; amido zinc(ii) phthalocyanine; benzene derivative; heterocyclic compound; phthalocyanine derivative; unclassified drug; zinc acetate; article; drug synthesis; matrix assisted laser desorption ionization time of flight mass spectrometry; proton nuclear magnetic resonance; reduction; substitution reaction
Año:2006
Número:5
Página de inicio:799
Página de fin:802
DOI: http://dx.doi.org/10.1055/s-2006-926336
Título revista:Synthesis
Título revista abreviado:Synthesis
ISSN:00397881
CODEN:SYNTB
CAS:zinc acetate, 557-34-6
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00397881_v_n5_p799_Strassert

Referencias:

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Citas:

---------- APA ----------
Strassert, C.A., Dicelio, L.E. & Awruch, J. (2006) . Reduction of an amido zinc(II) phthalocyanine by diborane. Synthesis(5), 799-802.
http://dx.doi.org/10.1055/s-2006-926336
---------- CHICAGO ----------
Strassert, C.A., Dicelio, L.E., Awruch, J. "Reduction of an amido zinc(II) phthalocyanine by diborane" . Synthesis, no. 5 (2006) : 799-802.
http://dx.doi.org/10.1055/s-2006-926336
---------- MLA ----------
Strassert, C.A., Dicelio, L.E., Awruch, J. "Reduction of an amido zinc(II) phthalocyanine by diborane" . Synthesis, no. 5, 2006, pp. 799-802.
http://dx.doi.org/10.1055/s-2006-926336
---------- VANCOUVER ----------
Strassert, C.A., Dicelio, L.E., Awruch, J. Reduction of an amido zinc(II) phthalocyanine by diborane. Synthesis. 2006(5):799-802.
http://dx.doi.org/10.1055/s-2006-926336