Abstract:
The particular behavior of 5β,6β steroidal epoxides carrying different groups at C-3 was studied. These epoxides may exhibit different cleavage behavior according to the nature of the solvent, the acid-base state of the medium, and the leaving abilities of the C-3 substituent. Results and alternative mechanisms are presented. © 1995.
Registro:
Documento: |
Artículo
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Título: | Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
Autor: | Gros, E.G. |
Filiación: | Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Buenos Aires, Argentina
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Palabras clave: | cleavage of epoxides; ring A steroidal elimination; steroidal epoxides; epoxide; lithium chloride; n,n dimethylacetamide; steroid; article; chemical reaction; degradation; ph; proton nuclear magnetic resonance; Cations; Epoxy Compounds; Lithium; Molecular Structure; Solvents; Steroids; Support, Non-U.S. Gov't |
Año: | 1995
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Volumen: | 60
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Número: | 7
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Página de inicio: | 434
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Página de fin: | 438
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DOI: |
http://dx.doi.org/10.1016/0039-128X(95)00032-L |
Título revista: | Steroids
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Título revista abreviado: | Steroids
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ISSN: | 0039128X
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CODEN: | STEDA
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CAS: | Cations; Epoxy Compounds; Lithium, 7439-93-2; Solvents; Steroids
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0039128X_v60_n7_p434_Gros |
Referencias:
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Citas:
---------- APA ----------
(1995)
. Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3. Steroids, 60(7), 434-438.
http://dx.doi.org/10.1016/0039-128X(95)00032-L---------- CHICAGO ----------
Gros, E.G.
"Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3"
. Steroids 60, no. 7
(1995) : 434-438.
http://dx.doi.org/10.1016/0039-128X(95)00032-L---------- MLA ----------
Gros, E.G.
"Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3"
. Steroids, vol. 60, no. 7, 1995, pp. 434-438.
http://dx.doi.org/10.1016/0039-128X(95)00032-L---------- VANCOUVER ----------
Gros, E.G. Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3. Steroids. 1995;60(7):434-438.
http://dx.doi.org/10.1016/0039-128X(95)00032-L