Abstract:
Carbon-13 nuclear magnetic resonance spectra for 31 Sβ-hydroxy and acetoxy androstane derivatives bearing vicinal oxygenated functions at ring D with and without oxygenated functions at C-6 are reported. Relative substituent effects are discussed. © 1991.
Registro:
Documento: |
Artículo
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Título: | Carbon-13 nuclear magnetic resonance spectral data of steroidal vicinal ketols and related compounds |
Autor: | Doller, D.; Gros, E.G. |
Filiación: | Departamento de Química Orgánica, Fucultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Buenos Aires, Argentina
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Palabras clave: | 16,17-Ketols; 13 C NMR; 13 C NMR spectral data; steroids; substituent-induced chemical shifts; α-ketols; androstane derivative; steroid; article; chemical structure; nuclear magnetic resonance; Androstanols; Magnetic Resonance Spectroscopy; Molecular Structure; Support, Non-U.S. Gov't |
Año: | 1991
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Volumen: | 56
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Número: | 4
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Página de inicio: | 168
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Página de fin: | 172
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DOI: |
http://dx.doi.org/10.1016/0039-128X(91)90077-9 |
Título revista: | Steroids
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Título revista abreviado: | Steroids
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ISSN: | 0039128X
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CODEN: | STEDA
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CAS: | Androstanols
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0039128X_v56_n4_p168_Doller |
Referencias:
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- Seldes, Gros, Acyl migration in the Reformatsky reaction of 21-acyloxy-5-pregnen-20-one derivatives with ethyl bromoacetate (1982) Steroids, 39, pp. 181-190
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- Numazawa, Nagaoka, Mutsumi, Stereospecific 1,2 hydride shift in the rearrangement of 16β-hydroxy-17-oxo steroids to 17β-hydroxy-16-ones with acid and base (1987) Chem Pharm Bull, 35, pp. 4763-4768
- Doller, Gros, Dissimilar behavior of 3β, 16α-dihydroxy-5α-androstan-17-one diacetate under basic and acidic conditions (1989) Helv Chim Acta, 72, pp. 1241-1247
- Patt, Shoolery, Attached proton test for C-13 NMR (1982) J Magn Reson, 46, pp. 535-539
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Citas:
---------- APA ----------
Doller, D. & Gros, E.G.
(1991)
. Carbon-13 nuclear magnetic resonance spectral data of steroidal vicinal ketols and related compounds. Steroids, 56(4), 168-172.
http://dx.doi.org/10.1016/0039-128X(91)90077-9---------- CHICAGO ----------
Doller, D., Gros, E.G.
"Carbon-13 nuclear magnetic resonance spectral data of steroidal vicinal ketols and related compounds"
. Steroids 56, no. 4
(1991) : 168-172.
http://dx.doi.org/10.1016/0039-128X(91)90077-9---------- MLA ----------
Doller, D., Gros, E.G.
"Carbon-13 nuclear magnetic resonance spectral data of steroidal vicinal ketols and related compounds"
. Steroids, vol. 56, no. 4, 1991, pp. 168-172.
http://dx.doi.org/10.1016/0039-128X(91)90077-9---------- VANCOUVER ----------
Doller, D., Gros, E.G. Carbon-13 nuclear magnetic resonance spectral data of steroidal vicinal ketols and related compounds. Steroids. 1991;56(4):168-172.
http://dx.doi.org/10.1016/0039-128X(91)90077-9