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Abstract:

Supplemented temperature/composition phase diagrams include the non-equilibrium glass-transition temperature (Tg) curve and equilibrium ice-melting and solubility curves. The inclusion of the non-equilibrium curve allows one to establish relationships with the time coordinate and, thus, with the dynamic behavior of systems, provided that the thermal history of such systems is known. The objective of this report is to contribute to the potential applications of supplemented state diagrams for aqueous glass-formers, in order to describe the influence of water content, nature of vitrifying agents, and temperature on the physico-chemical properties of foods and biological and pharmaceutical products. These data are helpful to develop formulations, processing strategies, or storage procedures in order to optimize the stability of food ingredients and pharmaceutical formulations. Reported experimental data on phase and state transitions for several food and pharmaceutical systems were analyzed. Some methodological aspects and the effect of phase and state transitions on the main potential chemical reactions that can alter those systems during processing and/or storage are discussed. © 2011 IUPAC.

Registro:

Documento: Artículo
Título:State diagrams for improving processing and storage of foods, biological materials, and pharmaceuticals (IUPAC Technical Report)
Autor:Buera, M.P.; Roos, Y.; Levine, H.; Slade, L.; Corti, H.R.; Reid, D.S.; Auffret, T.; Angell, C.A.
Filiación:Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Int, Cantilo s/n. Pabellón II Ciudad Universitaria, Buenos Aires, Argentina
School of Food and Nutritional Sciences, University College, Cork, Ireland
Food Polymer Science Consultancy (retired from Cereal Science, Kraft-Nabisco), Morris Plains, NJ 07950, United States
Department of Food Science and Technology, University of California at Davis, 1 Shields Avenue, Davis, CA 95616-8571, United States
taPrime Consulting, Sandwich, Kent, CT13 9JA, United Kingdom
Department of Chemistry, Arizona State University, Tempe, AZ 85287, United States
Palabras clave:Biomolecules; Glass transition; IUPAC Physical and Biophysical Chemistry Division; Phase/state diagrams; Reaction rates; Dynamic behaviors; Experimental data; Food ingredients; Glassformers; Influence of water; IUPAC Physical and Biophysical Chemistry Division; Methodological aspects; Non equilibrium; Pharmaceutical formulation; Pharmaceutical products; Pharmaceutical systems; Phase/state diagrams; Physicochemical property; Potential applications; Solubility curve; State diagram; State transitions; Thermal history; Time coordinates; Biological materials; Chemical contamination; Chemical properties; Drug products; Glass; Glass transition; Graphic methods; Ice; Molecular biology; Phase diagrams; Reaction rates; Thermal processing (foods); Water content; Food storage
Año:2011
Volumen:83
Número:8
Página de inicio:1567
Página de fin:1617
DOI: http://dx.doi.org/10.1351/PAC-REP-10-07-02
Título revista:Pure and Applied Chemistry
Título revista abreviado:Pure Appl. Chem.
ISSN:00334545
CODEN:PACHA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00334545_v83_n8_p1567_Buera

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Citas:

---------- APA ----------
Buera, M.P., Roos, Y., Levine, H., Slade, L., Corti, H.R., Reid, D.S., Auffret, T.,..., Angell, C.A. (2011) . State diagrams for improving processing and storage of foods, biological materials, and pharmaceuticals (IUPAC Technical Report). Pure and Applied Chemistry, 83(8), 1567-1617.
http://dx.doi.org/10.1351/PAC-REP-10-07-02
---------- CHICAGO ----------
Buera, M.P., Roos, Y., Levine, H., Slade, L., Corti, H.R., Reid, D.S., et al. "State diagrams for improving processing and storage of foods, biological materials, and pharmaceuticals (IUPAC Technical Report)" . Pure and Applied Chemistry 83, no. 8 (2011) : 1567-1617.
http://dx.doi.org/10.1351/PAC-REP-10-07-02
---------- MLA ----------
Buera, M.P., Roos, Y., Levine, H., Slade, L., Corti, H.R., Reid, D.S., et al. "State diagrams for improving processing and storage of foods, biological materials, and pharmaceuticals (IUPAC Technical Report)" . Pure and Applied Chemistry, vol. 83, no. 8, 2011, pp. 1567-1617.
http://dx.doi.org/10.1351/PAC-REP-10-07-02
---------- VANCOUVER ----------
Buera, M.P., Roos, Y., Levine, H., Slade, L., Corti, H.R., Reid, D.S., et al. State diagrams for improving processing and storage of foods, biological materials, and pharmaceuticals (IUPAC Technical Report). Pure Appl. Chem. 2011;83(8):1567-1617.
http://dx.doi.org/10.1351/PAC-REP-10-07-02