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Abstract:

A feature of solubility in near-critical fluids is its strong dependence on pressure and temperature. A general thermodynamic procedure which describes the distribution of solutes between two coexisting phases, may be conveniently employed to describe solubility in near-critical fluids. Asymptotic critical relations are a great help to evaluate data for volatile solutes, for solid solutes they help to separate contingent dependences of solubility from those which are essential. This analysis suggests there is no need to invoke the existence of critical clustering to explain the observed behaviour. © 1995 IUPAC

Registro:

Documento: Artículo
Título:Solubility in fluids close to their critical points
Autor:Fern´ndez-Prim, R.
Filiación:Departamento Quimica de Reactores, Comisión Nacional de Energia Atómica, Instituto de Quimica Fisica de Materiales, Ambiente y Energia, Facultad de Ciencias Exactas y Naturales, UBA, Ciudad Universitaria, Av. Libertador 8250, CP-1429, CP-1428, Buenos Aires, Argentina
Año:1995
Volumen:67
Número:4
Página de inicio:519
Página de fin:526
DOI: http://dx.doi.org/10.1351/pac199567040519
Título revista:Pure and Applied Chemistry
Título revista abreviado:Pure Appl. Chem.
ISSN:00334545
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00334545_v67_n4_p519_FernndezPrim

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Citas:

---------- APA ----------
(1995) . Solubility in fluids close to their critical points. Pure and Applied Chemistry, 67(4), 519-526.
http://dx.doi.org/10.1351/pac199567040519
---------- CHICAGO ----------
Fern´ndez-Prim, R. "Solubility in fluids close to their critical points" . Pure and Applied Chemistry 67, no. 4 (1995) : 519-526.
http://dx.doi.org/10.1351/pac199567040519
---------- MLA ----------
Fern´ndez-Prim, R. "Solubility in fluids close to their critical points" . Pure and Applied Chemistry, vol. 67, no. 4, 1995, pp. 519-526.
http://dx.doi.org/10.1351/pac199567040519
---------- VANCOUVER ----------
Fern´ndez-Prim, R. Solubility in fluids close to their critical points. Pure Appl. Chem. 1995;67(4):519-526.
http://dx.doi.org/10.1351/pac199567040519