Artículo
Prini, R.F. "Influence of thermodynamic variables and molecular parameters in the solubility of gases in liquids" (1990) Pure and Applied Chemistry. 62(11):2083-2090
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Abstract:
A semiempirical procedure based upon measurements of solubility over a reduced temperature range and the use of a perturbation method with a hard-sphere reference fluid, is able to describe satisfactorily the thermodynamics of dissolution of nonpolar gases in water over all the temperature range and for gas pressures up to 50 MPa. The procedure can also be applied to systems constituted by anisotropic molecules, either sphericallizing the intermolecular potential or employing the interaction site model. The possibility of extending these ideas to deal with the dissolution of gases exhibiting larger intermolecular interactions with the solvent is explored. © 1990 IUPAC
Registro:
| Documento: | Artículo |
| Título: | Influence of thermodynamic variables and molecular parameters in the solubility of gases in liquids |
| Autor: | Prini, R.F. |
| Filiación: | Departamento Química de Reactores, Comisión Nacional de Energía Atómica, Argentina Departamento Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Argentina |
| Año: | 1990 |
| Volumen: | 62 |
| Número: | 11 |
| Página de inicio: | 2083 |
| Página de fin: | 2090 |
| DOI: | http://dx.doi.org/10.1351/pac199062112083 |
| Título revista: | Pure and Applied Chemistry |
| Título revista abreviado: | Pure Appl. Chem. |
| ISSN: | 00334545 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00334545_v62_n11_p2083_Prini |
Referencias:
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- Verlet, L., Weis, J-J., (1972) Phys. Rev. A, 5, p. 939
- Pratt, L.R., Chandler, D., (1977) J. Chem. Phys, p. 3683
- Reed, T.M., Gubbins, K.E., (1973), Applied Statistical Mechanics, MacGraw-Hill Kogakusha, Tokyo; Fernández, R., (1990), Prini, High Temperature Aqueous Solutions: Thermodynamic Properties, CRC-Press; Alvarez, J., Fernández, R., Prini, to be published; Biggerstaff, B.R., White, D.E., Wood, R.H., (1985) J. Phys. Chem., 89, p. 4376
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- Biggerstaff, D.R., Wood, R.H., (1988) J. Phys. Chem, 92, pp. 1988-1994
- Fernández Prini, R., Crovetto, R., Japas, M.L., Laria, D., (1985) Acc, Chem. Res., 18, p. 207
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- Chandler, D., in The Liquid State of Matter, eds (1982) E.W. Montroll and J.L. Lebowitz. North-Holland, p. 275
- Laría, D., Fernández Prini, R., to be published; Wormald, C.J., Lancaster, N.M., (1988) J. Chem. Soc. Faraday I, 84, p. 3141
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Citas:
---------- APA ----------
(1990) . Influence of thermodynamic variables and molecular parameters in the solubility of gases in liquids. Pure and Applied Chemistry, 62(11), 2083-2090.http://dx.doi.org/10.1351/pac199062112083
---------- CHICAGO ----------
Prini, R.F. "Influence of thermodynamic variables and molecular parameters in the solubility of gases in liquids" . Pure and Applied Chemistry 62, no. 11 (1990) : 2083-2090.http://dx.doi.org/10.1351/pac199062112083
---------- MLA ----------
Prini, R.F. "Influence of thermodynamic variables and molecular parameters in the solubility of gases in liquids" . Pure and Applied Chemistry, vol. 62, no. 11, 1990, pp. 2083-2090.http://dx.doi.org/10.1351/pac199062112083
---------- VANCOUVER ----------
Prini, R.F. Influence of thermodynamic variables and molecular parameters in the solubility of gases in liquids. Pure Appl. Chem. 1990;62(11):2083-2090.http://dx.doi.org/10.1351/pac199062112083
