Abstract:
Fractionation of the Cetrimide salt of the sulphated polysaccharides of Nothogenia fastigiata led to the isolation of a complex product constituted by a xylogalactan sulphate and a xylomannan sulphate. Its structural study by methylation and desulphation-methylation analyses and 13C NMR spectroscopy indicated for the xylogalactan sulphate a backbone formed by 4-linked α-l-galactopyranose and 3-linked β-d-galactopyranose. The α-l-galactopyranosyl units are either 6-sulphated having single stubs of (1 → 3)-linked xylose or galactose, 3-sulphated or non-substituted. The β-d-galactopyranosyl residues are non-substituted or 4-sulphated. The xylomannan sulphate is similar to that previously isolated from this seaweed. © 1994.
Referencias:
- Cerezo, Lezerovich, Labriola, Rees, (1971) Carbohydr. Res., 19, p. 289
- Cerezo, (1972) Carbohydr. Res., 21, p. 209
- Matulewicz, Cerezo, Jarret, Syn, (1992) Int. J. Biol. Macromol., 14, p. 29
- Matulewicz, Cerezo, (1987) Phytochemistry, 26, p. 1033
- Matulewicz, Cerezo, (1987) Carbohydr. Polymers, 7, p. 121
- Haines, Matulewicz, Cerezo, (1990) Hydrobiologia, 204-205, p. 637
- Hakomori, (1964) J. Biochem. (Tokyo), 55, p. 205
- Haworth, (1915) J. Chem. Soc., 107, p. 8
- Usov, Elashvili, Polysaccharides of Algae. 44. Investigation of Sulfated Galactan from Laurencia nipponica Yamada (Rhodophyta, Rhodomelaceae) Using Partial Reductive Hydrolysis (1991) Botanica Marina, 34, p. 553
- Ruiz, Kamerling, Breg, Vliegenthart, (1988) Carbohydr. Res., 179, p. 411
- Lahaye, Yaphe, Rochas, (1985) Carbohydr. Res., 143, p. 240
- Joseleau, Chambat, Chumpitazi-Hermoza, (1981) Carbohydr. Res., 90, p. 339
- Furneaux, Stevenson, (1990) Hydrobiologia, 204-205, p. 615
- Dodgson, Price, (1962) Biochem. J., 84, p. 106
- Rees, 1022. Estimation of the relative amounts of isomeric sulphate esters in some sulphated polysaccharides (1961) Journal of the Chemical Society (Resumed), p. 5168
- Yaphe, Arsenault, (1965) Analyt. Biochem., 13, p. 143
- Seaman, Moore, Millet, (1964) Meth. Carbohydr. Chem., 3, p. 54
- Leontein, Lindberg, Lönngren, (1978) Carbohydr. Res., 62, p. 359
- Seymour, Chen, Bishop, (1979) Carbohydr. Res., 73, p. 19
- Lindberg, (1972) Meth. Enzymol., 28, p. 178
- Fleury, Lange, (1933) J. Pharm. Chim., 17, p. 107
Citas:
---------- APA ----------
Matulewicz, M.C., Haines, H.H. & Cerezo, A.A.
(1994)
. Sulphated xylogalactans from Nothogenia fastigiata. Phytochemistry, 36(1), 97-103.
http://dx.doi.org/10.1016/S0031-9422(00)97020-1---------- CHICAGO ----------
Matulewicz, M.C., Haines, H.H., Cerezo, A.A.
"Sulphated xylogalactans from Nothogenia fastigiata"
. Phytochemistry 36, no. 1
(1994) : 97-103.
http://dx.doi.org/10.1016/S0031-9422(00)97020-1---------- MLA ----------
Matulewicz, M.C., Haines, H.H., Cerezo, A.A.
"Sulphated xylogalactans from Nothogenia fastigiata"
. Phytochemistry, vol. 36, no. 1, 1994, pp. 97-103.
http://dx.doi.org/10.1016/S0031-9422(00)97020-1---------- VANCOUVER ----------
Matulewicz, M.C., Haines, H.H., Cerezo, A.A. Sulphated xylogalactans from Nothogenia fastigiata. Phytochemistry. 1994;36(1):97-103.
http://dx.doi.org/10.1016/S0031-9422(00)97020-1