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Abstract:

The steroids from the roots of Mandevilla pentlandiana were analysed. Six Δ20-steroids and four 6-keto-5α-stanols, novel as natural products, were isolated and characterized by spectroscopic methods. The plant also produces cardenolide glycosides, for which 20-hydroxysterols are known to be biosynthetic precursors. The hydroxylated derivatives have not been detected, but Δ20-derivatives, closely related to them, may be involved in that metabolic pathway. © 1991.

Registro:

Documento: Artículo
Título:Steroidal derivatives from the roots of mandevilla pentlandiana
Autor:Cabrera, G.; Palermo, J.A.; Seldes, A.M.; Gros, E.G.; Oberti, J.C.
Filiación:Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellon 2, Ciudad Universitaria, 1428 Buenos Aires, Argentina
Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Sucursal 16, Casilla 61, 5016 Córdoba, Argentina
Palabras clave:6-keto-5α-stanols.; Apocynaceae; Mandevilia pentlandiana; roots; Δ5,20 -diunsaturated sterols
Año:1991
Volumen:30
Número:4
Página de inicio:1239
Página de fin:1243
DOI: http://dx.doi.org/10.1016/S0031-9422(00)95209-9
Título revista:Phytochemistry
Título revista abreviado:Phytochemistry
ISSN:00319422
CODEN:PYTCA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00319422_v30_n4_p1239_Cabrera

Referencias:

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Citas:

---------- APA ----------
Cabrera, G., Palermo, J.A., Seldes, A.M., Gros, E.G. & Oberti, J.C. (1991) . Steroidal derivatives from the roots of mandevilla pentlandiana. Phytochemistry, 30(4), 1239-1243.
http://dx.doi.org/10.1016/S0031-9422(00)95209-9
---------- CHICAGO ----------
Cabrera, G., Palermo, J.A., Seldes, A.M., Gros, E.G., Oberti, J.C. "Steroidal derivatives from the roots of mandevilla pentlandiana" . Phytochemistry 30, no. 4 (1991) : 1239-1243.
http://dx.doi.org/10.1016/S0031-9422(00)95209-9
---------- MLA ----------
Cabrera, G., Palermo, J.A., Seldes, A.M., Gros, E.G., Oberti, J.C. "Steroidal derivatives from the roots of mandevilla pentlandiana" . Phytochemistry, vol. 30, no. 4, 1991, pp. 1239-1243.
http://dx.doi.org/10.1016/S0031-9422(00)95209-9
---------- VANCOUVER ----------
Cabrera, G., Palermo, J.A., Seldes, A.M., Gros, E.G., Oberti, J.C. Steroidal derivatives from the roots of mandevilla pentlandiana. Phytochemistry. 1991;30(4):1239-1243.
http://dx.doi.org/10.1016/S0031-9422(00)95209-9