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Abstract:

Fagara coco plants were inoculated in separate experiments with sodium acetate 1-14C, sodium formate-14C, mevalonic acid-4-14C, mevalonic acid-5-14C, 3,3-dimethylallyl alcohol-1-14C, and 3,3-dimethylacrylic acid-1-14C. The furanoquinoline alkaloid skimmianine was isolated from each plant and degraded to determine the activity at C-2 and C-3. The result from the acetate experiment confirmed previous findings for labelling only in the quinoline moiety; the same result was encountered with labelled dimethylacrylic acid. Sodium formate labelled mainly the methoxy groups, while the results from both mevalonic acids and dimethylallyl alcohol clearly indicated that C-2 and C-3 of the furan ring are derived from C-4 and C-5 of mevalonic acid respectively. © 1971.

Registro:

Documento: Artículo
Título:Biosynthesis of skimmianine in Fagara coco
Autor:Colonna, A.O.; Gros, E.G.
Filiación:Departmento de Quimíca Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Perú, 222 Buenos Aires, Argentina
Año:1971
Volumen:10
Número:7
Página de inicio:1515
Página de fin:1521
DOI: http://dx.doi.org/10.1016/0031-9422(71)85016-1
Título revista:Phytochemistry
Título revista abreviado:Phytochemistry
ISSN:00319422
CODEN:PYTCA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00319422_v10_n7_p1515_Colonna

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Citas:

---------- APA ----------
Colonna, A.O. & Gros, E.G. (1971) . Biosynthesis of skimmianine in Fagara coco. Phytochemistry, 10(7), 1515-1521.
http://dx.doi.org/10.1016/0031-9422(71)85016-1
---------- CHICAGO ----------
Colonna, A.O., Gros, E.G. "Biosynthesis of skimmianine in Fagara coco" . Phytochemistry 10, no. 7 (1971) : 1515-1521.
http://dx.doi.org/10.1016/0031-9422(71)85016-1
---------- MLA ----------
Colonna, A.O., Gros, E.G. "Biosynthesis of skimmianine in Fagara coco" . Phytochemistry, vol. 10, no. 7, 1971, pp. 1515-1521.
http://dx.doi.org/10.1016/0031-9422(71)85016-1
---------- VANCOUVER ----------
Colonna, A.O., Gros, E.G. Biosynthesis of skimmianine in Fagara coco. Phytochemistry. 1971;10(7):1515-1521.
http://dx.doi.org/10.1016/0031-9422(71)85016-1