Abstract:
The administration of sodium formate-14C to Fagara coco yielded, among other alkaloids, radioactive palmatine (I). Degradation of I clearly showed that almost 20% of the tracer was located on the berberine bridge carbon. © 1971.
Referencias:
- Gupta, Spenser, BIOSYNTHETIC INCORPORATION OF ONE-CARBON UNITS INTO BERBERINE AND HYDRASTINE (1965) Canadian Journal of Chemistry, 43, p. 133
- Battersby, Francis, Hirst, Stauton, (1963) Proc. Chem. Soc., p. 268
- Barton, Hesse, Kirby, 1185. Phenol oxidation and biosynthesis. Part VIII. Investigations on the biosynthesis of berberine and protopine (1965) Journal of the Chemical Society (Resumed), p. 6379
- Battersby, Francis, Ruveda, Stauton, (1965) Chem. Commun., p. 89
- Robinson, (1955) The Structural Relations of Natural Products, , Oxford University Press, London
- Colonna, Gros, (1971) Phytochem., 10, p. 1515
- Preininger, Hruban, Šimánek, Šantávy, Isolation and chemistry of the alkaloids from the plants of the genus Papaver. XLVI. The structure of the alkaloids PO-4, PO-5 and of the dehydrogenated α-coralydine (1970) Collection of Czechoslovak Chemical Communications, 35, p. 124
- Kuck, Albónico, Deulofeu, Escalante, (1967) Phytochem., 6, p. 1541
- Barton, Boar, Widdowson, Deulofeu, Albónico, J. Chem. Soc. (C) (1969) J. Chem. Soc. (C), p. 807
- Cava, Reed, (1965) Lloydia, 28, p. 73
- Späth, Quietensky, (1925) Berichte, 58, p. 2267
- Cava, Reed, (1967) J. Org. Chem., 32, p. 1640
Citas:
---------- APA ----------
Skerl, A.R. & Gros, E.G.
(1971)
. Biosynthesis of palmatine in Fagara coco. Phytochemistry, 10(11), 2719-2721.
http://dx.doi.org/10.1016/S0031-9422(00)97270-4---------- CHICAGO ----------
Skerl, A.R., Gros, E.G.
"Biosynthesis of palmatine in Fagara coco"
. Phytochemistry 10, no. 11
(1971) : 2719-2721.
http://dx.doi.org/10.1016/S0031-9422(00)97270-4---------- MLA ----------
Skerl, A.R., Gros, E.G.
"Biosynthesis of palmatine in Fagara coco"
. Phytochemistry, vol. 10, no. 11, 1971, pp. 2719-2721.
http://dx.doi.org/10.1016/S0031-9422(00)97270-4---------- VANCOUVER ----------
Skerl, A.R., Gros, E.G. Biosynthesis of palmatine in Fagara coco. Phytochemistry. 1971;10(11):2719-2721.
http://dx.doi.org/10.1016/S0031-9422(00)97270-4