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Abstract:

Density, sound velocity and refractive index of binary mixtures of water + 1,2-dimethoxyethane mixtures were measured over the whole composition range and at the temperature interval from 293.15 to 323.15 K. Obtained density data for the pure components agree, within experimental error, with published values. However, in the case of binary mixtures, strong discrepancies with values calculated from the equation proposed in the literature for this system are found. Excess functions, isentropic compressibility coefficients and thermal expansion coefficients were calculated from experimental data. Partial molar volumes were obtained employing the exponential representation previously proposed by us which shows better results than the usual polynomial approach. Results are discussed on the grounds of the molecular characteristics obtained from Raman and NMR spectroscopy determinations on this system. © 2014, © 2014 Taylor & Francis.

Registro:

Documento: Artículo
Título:Density, sound velocity and refractive index in the water + 1,2-dimethoxyethane system
Autor:Grande, M.C.; Alvarez Juliá, J.; Barrero, C.R.; Marschoff, C.M.
Filiación:Departamento de Química, Universidad de Buenos Aires, Buenos Aires, 1063, Argentina
Departamento de Matemática, Universidad de Buenos Aires, Buenos Aires, 1063, Argentina
Departamento de Ingeniería Química, Universidad de Buenos Aires, Pabellón de Industrias, Ciudad Universitaria, Buenos Aires, 1428, Argentina
Palabras clave:binary solutions; density; isentropic compressibility; partial molar volumes; refractive index; sound velocity; thermal expansion coefficient; Acoustic wave velocity; Compressibility; Density (specific gravity); Nuclear magnetic resonance spectroscopy; Refractive index; Thermal expansion; Volume measurement; Binary solutions; Exponential representation; Isentropic compressibility; Molecular characteristics; Partial Molar volume; Polynomial approach; Temperature intervals; Thermal expansion coefficients; Binary mixtures
Año:2015
Volumen:53
Número:3
Página de inicio:403
Página de fin:417
DOI: http://dx.doi.org/10.1080/00319104.2014.990964
Título revista:Physics and Chemistry of Liquids
Título revista abreviado:Phys. Chem. Liq.
ISSN:00319104
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00319104_v53_n3_p403_Grande

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Citas:

---------- APA ----------
Grande, M.C., Alvarez Juliá, J., Barrero, C.R. & Marschoff, C.M. (2015) . Density, sound velocity and refractive index in the water + 1,2-dimethoxyethane system. Physics and Chemistry of Liquids, 53(3), 403-417.
http://dx.doi.org/10.1080/00319104.2014.990964
---------- CHICAGO ----------
Grande, M.C., Alvarez Juliá, J., Barrero, C.R., Marschoff, C.M. "Density, sound velocity and refractive index in the water + 1,2-dimethoxyethane system" . Physics and Chemistry of Liquids 53, no. 3 (2015) : 403-417.
http://dx.doi.org/10.1080/00319104.2014.990964
---------- MLA ----------
Grande, M.C., Alvarez Juliá, J., Barrero, C.R., Marschoff, C.M. "Density, sound velocity and refractive index in the water + 1,2-dimethoxyethane system" . Physics and Chemistry of Liquids, vol. 53, no. 3, 2015, pp. 403-417.
http://dx.doi.org/10.1080/00319104.2014.990964
---------- VANCOUVER ----------
Grande, M.C., Alvarez Juliá, J., Barrero, C.R., Marschoff, C.M. Density, sound velocity and refractive index in the water + 1,2-dimethoxyethane system. Phys. Chem. Liq. 2015;53(3):403-417.
http://dx.doi.org/10.1080/00319104.2014.990964