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Abstract:

The 13C NMR spectra of sixteen 4‐ene‐3‐keto‐ and 1,4‐diene‐3‐keto corticosteroids are described. Substituent shifts and the effect of added methanol‐d4 are reported, and conformational distortions and intramolecular hydrogen bonding are analysed based on these data. Copyright © 1984 Wiley Heyden Ltd.

Registro:

Documento: Artículo
Título:A carbon‐13 nuclear magnetic resonance study of the 1,4‐diene analogues of steroid hormones and related steroids
Autor:Gonzalez, M.D.; Burton, G.
Filiación:Departamento de Química Orgánica, Facultad de Ciencias Exactas Y Naturales, Universidad de Buenos Aires, Umymfor, Conicet, Fcen, Argentina
Conicet, Fcen, Ciudad Universitaria, Pabellón 2, Buenos Aires, 1428, Argentina
Año:1984
Volumen:22
Número:9
Página de inicio:586
Página de fin:591
DOI: http://dx.doi.org/10.1002/mrc.1270220914
Título revista:Organic Magnetic Resonance
Título revista abreviado:Magn. Reson. Chem.
ISSN:00304921
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00304921_v22_n9_p586_Gonzalez

Referencias:

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  • Roldán, A., Burton, G., Castillo, M., Damasco, M.C., Lantos, C.P., (1981) J. Steroid Biochem., 15, p. 467
  • Blunt, J.W., Stothers, J.B., 13C n.m.r. spectra of steroids —a survey and commentary (1977) Organic Magnetic Resonance, 9, p. 439
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  • Bhacca, N.S., Giannini, D.D., Jankowski, W.S., Wolff, M.E., Substituent effects in carbon-13 nuclear magnetic resonance spectroscopy. Progesterone, deoxycorticosterone, corticosterone, cortisol, and related steroids (1973) Journal of the American Chemical Society, 95, p. 8421
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Citas:

---------- APA ----------
Gonzalez, M.D. & Burton, G. (1984) . A carbon‐13 nuclear magnetic resonance study of the 1,4‐diene analogues of steroid hormones and related steroids. Organic Magnetic Resonance, 22(9), 586-591.
http://dx.doi.org/10.1002/mrc.1270220914
---------- CHICAGO ----------
Gonzalez, M.D., Burton, G. "A carbon‐13 nuclear magnetic resonance study of the 1,4‐diene analogues of steroid hormones and related steroids" . Organic Magnetic Resonance 22, no. 9 (1984) : 586-591.
http://dx.doi.org/10.1002/mrc.1270220914
---------- MLA ----------
Gonzalez, M.D., Burton, G. "A carbon‐13 nuclear magnetic resonance study of the 1,4‐diene analogues of steroid hormones and related steroids" . Organic Magnetic Resonance, vol. 22, no. 9, 1984, pp. 586-591.
http://dx.doi.org/10.1002/mrc.1270220914
---------- VANCOUVER ----------
Gonzalez, M.D., Burton, G. A carbon‐13 nuclear magnetic resonance study of the 1,4‐diene analogues of steroid hormones and related steroids. Magn. Reson. Chem. 1984;22(9):586-591.
http://dx.doi.org/10.1002/mrc.1270220914