THE usual reaction product of the treatment of the acylated nitriles of aldonic acids with ammonia are the aldose diacetamides1. A variation of this reaction was found when Hockett and Chandler2, by treating hexa-acetyl-D-α-glucoheptonic acid nitrile with ammonia, obtained N-acetyl-D-glucofuranosylamine. The same product resulted from the action of ammonia on penta-acetyl-aldehydo-D-glucose. Later, Niemann and Hays3 prepared N-acetyl-D-glucofuranosylamine by the action of methanolic ammonia on penta-acetyl-D-β-glucose, a reaction that produced the transformation of the original pyranose ring of the acetylated glucose into a furanose structure. © 1951 Nature Publishing Group.
| Documento: | Artículo |
| Título: | Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19] |
| Autor: | Deulofeu, V.; Deferrari, J.O. |
| Filiación: | Cátedra de Quimica Biológica, Facultad de Ciencias Médicas, Facultad de Ciencias Exactas, Fisicas y Naturales, Buenos Aires |
| Idioma: | Inglés |
| Palabras clave: | glucose; article; GLUCOSE; Glucose |
| Año: | 1951 |
| Volumen: | 167 |
| Número: | 4236 |
| Página de inicio: | 42 |
| DOI: | http://dx.doi.org/10.1038/167042a0 |
| Título revista: | Nature |
| ISSN: | 00280836 |
| CAS: | glucose, 50-99-7, 84778-64-3; Glucose, 50-99-7 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00280836_v167_n4236_p42_Deulofeu |
