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Abstract:

THE usual reaction product of the treatment of the acylated nitriles of aldonic acids with ammonia are the aldose diacetamides1. A variation of this reaction was found when Hockett and Chandler2, by treating hexa-acetyl-D-α-glucoheptonic acid nitrile with ammonia, obtained N-acetyl-D-glucofuranosylamine. The same product resulted from the action of ammonia on penta-acetyl-aldehydo-D-glucose. Later, Niemann and Hays3 prepared N-acetyl-D-glucofuranosylamine by the action of methanolic ammonia on penta-acetyl-D-β-glucose, a reaction that produced the transformation of the original pyranose ring of the acetylated glucose into a furanose structure. © 1951 Nature Publishing Group.

Registro:

Documento: Artículo
Título:Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]
Autor:Deulofeu, V.; Deferrari, J.O.
Filiación:Cátedra de Quimica Biológica, Facultad de Ciencias Médicas, Facultad de Ciencias Exactas, Fisicas y Naturales, Buenos Aires
Idioma: Inglés
Palabras clave:glucose; article; GLUCOSE; Glucose
Año:1951
Volumen:167
Número:4236
Página de inicio:42
DOI: http://dx.doi.org/10.1038/167042a0
Título revista:Nature
ISSN:00280836
CAS:glucose, 50-99-7, 84778-64-3; Glucose, 50-99-7
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00280836_v167_n4236_p42_Deulofeu

Citas:

---------- APA ----------
Deulofeu, V. & Deferrari, J.O. (1951) . Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]. Nature, 167(4236), 42.
http://dx.doi.org/10.1038/167042a0
---------- CHICAGO ----------
Deulofeu, V., Deferrari, J.O. "Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]" . Nature 167, no. 4236 (1951) : 42.
http://dx.doi.org/10.1038/167042a0
---------- MLA ----------
Deulofeu, V., Deferrari, J.O. "Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]" . Nature, vol. 167, no. 4236, 1951, pp. 42.
http://dx.doi.org/10.1038/167042a0
---------- VANCOUVER ----------
Deulofeu, V., Deferrari, J.O. Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]. 1951;167(4236):42.
http://dx.doi.org/10.1038/167042a0