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Abstract:

Anion polarizabilities in alkali halide crystals are analysed as a function of interionic separation R. The anion polarizability is treated as a function of the anion and cation radii, with its partial derivatives approximated by those with respect to R for fixed cation and anion, respectively. With pressure derivatives of the ionic radii deduced from the crystal compressibility, assuming transferability among crystals, the polarizability derivatives with respect to ionic radius yield pressure derivatives of the polarizability that agree with experiment to within a factor of two. These results offer a useful means of predicting the pressure dependence of dielectric data. © 1997 Taylor & Francis Group, LLC.

Registro:

Documento: Artículo
Título:Anion polarizability functions in alkali halide crystals
Autor:Batana, A.; Bruno, J.; Munn, R.W.
Filiación:Departamento de Quimica Inorganica, Analitica y Quimica Fisica, Faculdad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina
Department of Chemistry, UMIST, Manchester, M60 1QD, Argentina
Año:1997
Volumen:92
Número:6
Página de inicio:1029
Página de fin:1034
DOI: http://dx.doi.org/10.1080/002689797169646
Título revista:Molecular Physics
Título revista abreviado:Mol. Phys.
ISSN:00268976
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00268976_v92_n6_p1029_Batana

Referencias:

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Citas:

---------- APA ----------
Batana, A., Bruno, J. & Munn, R.W. (1997) . Anion polarizability functions in alkali halide crystals. Molecular Physics, 92(6), 1029-1034.
http://dx.doi.org/10.1080/002689797169646
---------- CHICAGO ----------
Batana, A., Bruno, J., Munn, R.W. "Anion polarizability functions in alkali halide crystals" . Molecular Physics 92, no. 6 (1997) : 1029-1034.
http://dx.doi.org/10.1080/002689797169646
---------- MLA ----------
Batana, A., Bruno, J., Munn, R.W. "Anion polarizability functions in alkali halide crystals" . Molecular Physics, vol. 92, no. 6, 1997, pp. 1029-1034.
http://dx.doi.org/10.1080/002689797169646
---------- VANCOUVER ----------
Batana, A., Bruno, J., Munn, R.W. Anion polarizability functions in alkali halide crystals. Mol. Phys. 1997;92(6):1029-1034.
http://dx.doi.org/10.1080/002689797169646