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Abstract:

Direct inlet mass spectrometry (DI-MS) was examined for its suitability to quickly identify indigo in mixtures with lipidic and proteinaceous binders, such as those characteristic of paintings and polychromy. The technique was tested on naturally aged reference mixtures of indigo with linseed oil, rabbit skin glue, and whole egg. DI-MS with electron ionization at 70. eV served as an efficient tool for screening indigo in complex matrices and provided, at the same time, a mass spectral fingerprint of the organic binder in just a few minutes. The technique was applied to the identification of indigo in a blue sample from a mural painting dated from the 18th century and housed in an Andean church in Bolivia. At the same time, the acquired data revealed for the first time the use of an egg tempera binding medium in an Andean mural painting. © 2015 Elsevier B.V.

Registro:

Documento: Artículo
Título:Direct inlet mass spectrometry for a rapid characterization of indigo in lipidic and proteinaceous matrices
Autor:Gómez, B.A.; Rodríguez, D.C.; Careaga, V.P.; Siracusano, G.; Maier, M.S.
Filiación:Facultad de Ciencias Exactas y Naturales, UMYMFOR-CONICET and Departamento de Química Orgánica, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Ciudad Autónoma de Buenos Aires, C1428EGA, Argentina
Centro de Investigación en Arte, Materia y Cultura (IIAC), Universidad Nacional de Tres de Febrero, Avda. Antártida Argentina 1355, Ciudad Autónoma de Buenos Aires, C1104ACA, Argentina
CONICET, Rivadavia 1917, Ciudad Autónoma de Buenos Aires, C1033AAJ, Argentina
Palabras clave:Colonial art; Direct inlet mass spectrometry; Indigo; Lipids; Proteins
Año:2016
Volumen:125
Página de inicio:21
Página de fin:28
DOI: http://dx.doi.org/10.1016/j.microc.2015.11.006
Título revista:Microchemical Journal
Título revista abreviado:Microchem. J.
ISSN:0026265X
CODEN:MICJA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0026265X_v125_n_p21_Gomez

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Citas:

---------- APA ----------
Gómez, B.A., Rodríguez, D.C., Careaga, V.P., Siracusano, G. & Maier, M.S. (2016) . Direct inlet mass spectrometry for a rapid characterization of indigo in lipidic and proteinaceous matrices. Microchemical Journal, 125, 21-28.
http://dx.doi.org/10.1016/j.microc.2015.11.006
---------- CHICAGO ----------
Gómez, B.A., Rodríguez, D.C., Careaga, V.P., Siracusano, G., Maier, M.S. "Direct inlet mass spectrometry for a rapid characterization of indigo in lipidic and proteinaceous matrices" . Microchemical Journal 125 (2016) : 21-28.
http://dx.doi.org/10.1016/j.microc.2015.11.006
---------- MLA ----------
Gómez, B.A., Rodríguez, D.C., Careaga, V.P., Siracusano, G., Maier, M.S. "Direct inlet mass spectrometry for a rapid characterization of indigo in lipidic and proteinaceous matrices" . Microchemical Journal, vol. 125, 2016, pp. 21-28.
http://dx.doi.org/10.1016/j.microc.2015.11.006
---------- VANCOUVER ----------
Gómez, B.A., Rodríguez, D.C., Careaga, V.P., Siracusano, G., Maier, M.S. Direct inlet mass spectrometry for a rapid characterization of indigo in lipidic and proteinaceous matrices. Microchem. J. 2016;125:21-28.
http://dx.doi.org/10.1016/j.microc.2015.11.006