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Abstract:

Analytical characterization of reference carbon-based black pigments has been performed using Fourier transform infrared spectroscopy (FTIR) with attenuated total reflectance (ATR) and scanning electron microscopy (SEM) coupled to an energy-dispersive X-ray spectrometer (EDS). The unambiguous identification of these pigments, which are found in paintings, rock art and archeological artifacts, still remains a big challenge due to the variety of sources and manufacturing processes used in their preparation. The analytical results achieved in this study allowed us to discriminate between carbon-based pigments from different sources and detect adulterations. The methodological approach was successfully applied to the identification of vegetable charcoal and bone black in two colonial paintings dated from the eighteenth century. Conclusions regarding the pictorial techniques were drawn from FTIR data. © 2011 Elsevier B.V.

Registro:

Documento: Artículo
Título:Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment
Autor:Tomasini, E.; Siracusano, G.; Maier, M.S.
Filiación:UMYMFOR and Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, (1428) Ciudad Autónoma de Buenos Aires, Argentina
CONICET, Universidad Nacional de San Martín, B. Quinquela Martín 1784, (1296) Ciudad Autónoma de Buenos Aires, Argentina
Palabras clave:ATR; Carbon black; Carbon-based pigments; Colonial art; FTIR; SEM-EDS
Año:2012
Volumen:102
Página de inicio:28
Página de fin:37
DOI: http://dx.doi.org/10.1016/j.microc.2011.11.005
Título revista:Microchemical Journal
Título revista abreviado:Microchem. J.
ISSN:0026265X
CODEN:MICJA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0026265X_v102_n_p28_Tomasini

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Citas:

---------- APA ----------
Tomasini, E., Siracusano, G. & Maier, M.S. (2012) . Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment. Microchemical Journal, 102, 28-37.
http://dx.doi.org/10.1016/j.microc.2011.11.005
---------- CHICAGO ----------
Tomasini, E., Siracusano, G., Maier, M.S. "Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment" . Microchemical Journal 102 (2012) : 28-37.
http://dx.doi.org/10.1016/j.microc.2011.11.005
---------- MLA ----------
Tomasini, E., Siracusano, G., Maier, M.S. "Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment" . Microchemical Journal, vol. 102, 2012, pp. 28-37.
http://dx.doi.org/10.1016/j.microc.2011.11.005
---------- VANCOUVER ----------
Tomasini, E., Siracusano, G., Maier, M.S. Spectroscopic, morphological and chemical characterization of historic pigments based on carbon. Paths for the identification of an artistic pigment. Microchem. J. 2012;102:28-37.
http://dx.doi.org/10.1016/j.microc.2011.11.005