Artículo

La versión final de este artículo es de uso interno. El editor solo permite incluir en el repositorio el artículo en su versión post-print. Por favor, si usted la posee enviela a
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

A mathematical model was proposed to simulate simultaneous sulfur dioxide absorption and reaction during corn steeping. The parameters of the model, the diffusion coefficient and the reaction rate constant, were determined. The reaction rate of sulfur dioxide in corn grain followed first-order kinetics, with rate constants in the range 1.49×10-7to 9.78×10-7s-1for steeping temperatures from 25 to 55 °C. The Arrhenius activation energy for sulfur dioxide loss was 60.5 kJ/mol. The fitting of the mathematical model to the absorption curves determined the diffusion coefficient of sulfur dioxide in corn kernels. These varied from 1.17×10-11to 5.18×10-11m2/s for the temperature range 25-55 °C. Temperature-dependent diffusion coefficients was shown to obey the Arrhenius equation with an activation energy of 39.8 kJ/mol. © 2001 Academic Press.

Registro:

Documento: Artículo
Título:Absorption Kinetics of Sulfur Dioxide in Flint Corn during Steeping
Autor:Haros, C.M.; Aguerre, R.J.; Suarez, C.
Filiación:Departamento de Industrias, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina
Departamento de Tecnología, Universidad Nacional de Luján, C.C. 221-6700 Luján, Pcia. de Buenos Aires, Argentina
Palabras clave:Corn steeping; sulfur dioxide absorption; sulfur dioxide reaction; Arrhenius; Zea mays
Año:2001
Volumen:34
Número:5
Página de inicio:293
Página de fin:298
DOI: http://dx.doi.org/10.1006/fstl.2001.0770
Título revista:LWT - Food Science and Technology
Título revista abreviado:LWT - Food Sci. Technol.
ISSN:00236438
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00236438_v34_n5_p293_Haros

Referencias:

  • (1980) Total Solids (Moisture, Indirect Methods), , AOAC, Association of Official Analytical Chemist, Washington, D.C
  • Becker, H.A., On the absorption of liquid water by the wheat kernel (1960) Cereal Chemistry, 37, pp. 309-323
  • Bolin, H.R., Boyle, F.P., Effect of storage and processing on sulfur dioxide in preserved fruits (1972) Food Products Development, 6, pp. 84-86
  • Cox, M.J., McMasters, M.M., Hilbert, G., Effect of the sulfurous acid steep in corn wet-milling (1944) Cereal Chemistry, 21, pp. 447-465
  • Crank, J., (1957) The Mathematics of Diffusion, , London: Oxford University Press
  • Eckhoff, S.R., Okos, M.R., Kinetics of sulfite reaction in corn grain (1986) Journal of Agriculture and Food Chemistry, 34, pp. 239-245
  • Eckhoff, S.R., Okos, M.R., Sorption kinetics of sulfur dioxide on yellow dent corn (1990) Transactions of the ASAE, 33, pp. 855-861
  • Fan, L.T., Chung, D.S., Shellenberger, J.A., Diffusion coefficients of water in wheat kernels (1961) Cereal Chemistry, 38, pp. 540-548
  • Fan, L.T., Chu, P.S., Shellenberger, J.A., Diffusion of water in kernels of corn and sorghum (1963) Cereal Chemistry, 40, pp. 303-313
  • Fan, L.T., Chen, H.C., Shellenberger, J.A., Chung, D.S., Comparison of the rates of absorption of water by corn kernels with and without dissolved sulfur dioxide (1965) Cereal Chemistry, 42, pp. 385-596
  • Haros, M., Suarez, C., Effect of drying, initial moisture and variety in corn wet milling (1998) Journal of Food Engineering, 34, pp. 473-481
  • Haros, C.M., Viollaz, P.E., Suárez, C., Effect of temperature and SO2on the rates of water absorption on three maize hybrids (1995) Journal of Food Engineering, 25, pp. 473-482
  • Legault, R.R., Hendel, C.E., Talburt, W.F., Rasnussan, L.B., Sulfite disappearance in dehydrated vegetable during storage (1949) Industrial and Engineering Chemistry, 41, pp. 1447-1451
  • Maga, J.A., Cereal volatiles, a review (1978) Journal of Agriculture and Food Chemistry, 26, pp. 175-178
  • Muthukumarappan, K., Gunasekaran, S., Vapor diffusivity and hygroscopic expansion of corn kernels during adsorption (1990) Transactions of the ASAE, 33, pp. 1637-1641
  • Parti, M., Dugmanics, I., Diffusion coefficient for corn grain (1990) Transactions of the ASAE, 33, pp. 1652-1656
  • Ponting, J.D., Johson, G., Determination of sulfur dioxide in fruits (1945) Industrial and Engineering Chemistry, 17, pp. 682-686
  • Perry, R.H., Chilton, C.H., (1973) Chemical Engineering Handbook, , Tokyo: International Student ed. McGraw Hill Kogakusha, Ltd
  • Robutti, J.L., Observaciones de microscopía electrónica de barrido sobre endosperma de la línea endócrina P21de maíz (1980) Boletín de Divulgación Técnica N°, , Instituto Nacional de Tecnología Agropecuaria (INTA)
  • Robutti, J.L., Borras, F.S., Eyherabide, G.H., Zein composition of mechanically separated coarse and fine portions of maize kernels (1997) Cereal Chemistry, 74, pp. 75-78
  • Rodriguez, N., Zaritzky, N.E., Modeling of sulfur dioxide uptake in pre-peeled potatoes of different geometrical shapes (1986) Journal of Food Science, 51, pp. 618-622
  • Rossello, C., Cañellas, J., Santiesteban, I., Mulet, A., Simulation of the absorption process of sulphur dioxide in apricots (1993) Lebensmittel-Wissenschaft Und-technologie, 26, pp. 322-328
  • Schreoter, L.C., (1966) Sulfur Dioxide Applications in Foods, Beverages and Pharmaceuticals, , Oxford: Pergamon Press

Citas:

---------- APA ----------
Haros, C.M., Aguerre, R.J. & Suarez, C. (2001) . Absorption Kinetics of Sulfur Dioxide in Flint Corn during Steeping. LWT - Food Science and Technology, 34(5), 293-298.
http://dx.doi.org/10.1006/fstl.2001.0770
---------- CHICAGO ----------
Haros, C.M., Aguerre, R.J., Suarez, C. "Absorption Kinetics of Sulfur Dioxide in Flint Corn during Steeping" . LWT - Food Science and Technology 34, no. 5 (2001) : 293-298.
http://dx.doi.org/10.1006/fstl.2001.0770
---------- MLA ----------
Haros, C.M., Aguerre, R.J., Suarez, C. "Absorption Kinetics of Sulfur Dioxide in Flint Corn during Steeping" . LWT - Food Science and Technology, vol. 34, no. 5, 2001, pp. 293-298.
http://dx.doi.org/10.1006/fstl.2001.0770
---------- VANCOUVER ----------
Haros, C.M., Aguerre, R.J., Suarez, C. Absorption Kinetics of Sulfur Dioxide in Flint Corn during Steeping. LWT - Food Sci. Technol. 2001;34(5):293-298.
http://dx.doi.org/10.1006/fstl.2001.0770