Artículo
Grotewold, J.; Lissi, E.A.; Villa, A.E. "Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine" (1966) Journal of the Chemical Society A: Inorganic, Physical, Theoretical:1034-1037
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Abstract:
The reaction between borine carbonyl and trimethylamine has been studied from 207·3 to 273·2°K. Below 273·2°K the reaction is second-order: d(CO)/dt = k(BH3CO)(Me3N). The Arrhenius parameters associated with this SN2 reaction are E = 8·60 ± 0·30 kcal./mole, and A = 10 9·82 ± 0·27 c.c./mole sec. At 273·2°K the unimolecular rupture of the B-C bond becomes important as a rate-controlling step.
Registro:
| Documento: | Artículo |
| Título: | Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine |
| Autor: | Grotewold, J.; Lissi, E.A.; Villa, A.E. |
| Filiación: | Department of Inorganic Chemistry, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Perú 22, Buenos Aires, Argentina |
| Año: | 1966 |
| Página de inicio: | 1034 |
| Página de fin: | 1037 |
| DOI: | http://dx.doi.org/10.1039/J19660001034 |
| Título revista: | Journal of the Chemical Society A: Inorganic, Physical, Theoretical |
| ISSN: | 00224944 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00224944_v_n_p1034_Grotewold |
Citas:
---------- APA ----------
Grotewold, J., Lissi, E.A. & Villa, A.E. (1966) . Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine. Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1034-1037.http://dx.doi.org/10.1039/J19660001034
---------- CHICAGO ----------
Grotewold, J., Lissi, E.A., Villa, A.E. "Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine" . Journal of the Chemical Society A: Inorganic, Physical, Theoretical (1966) : 1034-1037.http://dx.doi.org/10.1039/J19660001034
---------- MLA ----------
Grotewold, J., Lissi, E.A., Villa, A.E. "Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine" . Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1966, pp. 1034-1037.http://dx.doi.org/10.1039/J19660001034
---------- VANCOUVER ----------
Grotewold, J., Lissi, E.A., Villa, A.E. Reactions of co-ordinated boron compounds in the gas phase. Part I. Borine carbonyl and trimethylamine. 1966:1034-1037.http://dx.doi.org/10.1039/J19660001034
