Abstract:
The co-condensation in situ of tetraethoxysilane (TEOS) and mercaptopropyltrimethoxysilane (MPTMS) using cetyltrimethylammonium bromide (CTAB) as a template results in the synthesis of multilayered mesoporous structured SiO 2 colloids with onion-like chemical environments. Thiol groups were anchored to an inner selected SiO 2 porous layer in a bilayered core shell particle producing different chemical regions inside the colloidal layered structure. X-Ray Photoelectron Spectroscopy (XPS) shows a preferential anchoring of the SH groups in the double layer shell system, while porosimetry and simple chemical modifications confirm that pores are accessible. We can envision the synthesis of interesting colloidal objects with defined chemical environments with highly controlled properties. © 2012 Elsevier Inc. © 2012 Elsevier Inc. All rights reserved.
Registro:
Documento: |
Artículo
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Título: | Organized thiol functional groups in mesoporous core shell colloids |
Autor: | Marchena, M.H.; Granada, M.; Bordoni, A.V.; Joselevich, M.; Troiani, H.; Williams, F.J.; Wolosiuk, A. |
Filiación: | Gerencia Química, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica (CNEA), Avda. Gral. Paz 1499, B1650KNA Buenos Aires, Argentina Centro Atómico Bariloche - CNEA, 8400 San Carlos de Bariloche, Argentina Instituto Balseiro - Centro Atómico Bariloche - CNEA, San Carlos de Bariloche 8400, Argentina Asociación Civil Expedición Ciencia, Cabrera 4948, C1414BGP Buenos Aires, Argentina DQIAQyF - INQUIMAE FCEN, Universidad de Buenos Aires, Ciudad Universitaria, C1428EHA Buenos Aires, Argentina Gerenciade Área de Energía Nuclear, Centro Atómico Constituyentes-CNEA, Av. Gral Paz 1499, B1650KNA Buenos Aires, Argentina
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Palabras clave: | Colloids; Coreshell; Mesoporous silica; Templated materials; Thiols; Cetyltrimethylammonium bromide; Chemical environment; Co-condensation; Controlled properties; Core shell particles; Core-shell; Double layers; In-situ; Layered Structures; Mercaptopropyltrimethoxysilane; Mesoporous; Mesoporous Silica; Multi-layered; Porosimetry; Porous layers; SH groups; Templated materials; Tetraethoxysilanes; Thiol functional groups; Thiol groups; Thiols; Colloid chemistry; Colloids; Functional groups; Silicon compounds; X ray photoelectron spectroscopy; Chemical modification |
Año: | 2012
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Volumen: | 187
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Página de inicio: | 97
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Página de fin: | 102
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DOI: |
http://dx.doi.org/10.1016/j.jssc.2011.12.028 |
Título revista: | Journal of Solid State Chemistry
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Título revista abreviado: | J. Solid State Chem.
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ISSN: | 00224596
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CODEN: | JSSCB
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00224596_v187_n_p97_Marchena |
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Citas:
---------- APA ----------
Marchena, M.H., Granada, M., Bordoni, A.V., Joselevich, M., Troiani, H., Williams, F.J. & Wolosiuk, A.
(2012)
. Organized thiol functional groups in mesoporous core shell colloids. Journal of Solid State Chemistry, 187, 97-102.
http://dx.doi.org/10.1016/j.jssc.2011.12.028---------- CHICAGO ----------
Marchena, M.H., Granada, M., Bordoni, A.V., Joselevich, M., Troiani, H., Williams, F.J., et al.
"Organized thiol functional groups in mesoporous core shell colloids"
. Journal of Solid State Chemistry 187
(2012) : 97-102.
http://dx.doi.org/10.1016/j.jssc.2011.12.028---------- MLA ----------
Marchena, M.H., Granada, M., Bordoni, A.V., Joselevich, M., Troiani, H., Williams, F.J., et al.
"Organized thiol functional groups in mesoporous core shell colloids"
. Journal of Solid State Chemistry, vol. 187, 2012, pp. 97-102.
http://dx.doi.org/10.1016/j.jssc.2011.12.028---------- VANCOUVER ----------
Marchena, M.H., Granada, M., Bordoni, A.V., Joselevich, M., Troiani, H., Williams, F.J., et al. Organized thiol functional groups in mesoporous core shell colloids. J. Solid State Chem. 2012;187:97-102.
http://dx.doi.org/10.1016/j.jssc.2011.12.028