Abstract:
For ionic crystals of NaCl and CsCl structures, the volume dependence of the effective ionic charge ( d ln s d ln V) defined by the second Szigeti relation is calculated using low temperature experimental data. The need for experimental data of γT at T→ 0°K is remarked upon. ( d ln s d ln V) obtained independently with a deformation dipole model and a simple shell model. The results are compared. All models tend to give positive values of ( d ln s d ln V), as expected. © 1984.
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Citas:
---------- APA ----------
Batana, A. & Faour, J.
(1984)
. Pressure dependence of the effective charge of ionic crystals. Journal of Physics and Chemistry of Solids, 45(5), 571-574.
http://dx.doi.org/10.1016/0022-3697(84)90093-3---------- CHICAGO ----------
Batana, A., Faour, J.
"Pressure dependence of the effective charge of ionic crystals"
. Journal of Physics and Chemistry of Solids 45, no. 5
(1984) : 571-574.
http://dx.doi.org/10.1016/0022-3697(84)90093-3---------- MLA ----------
Batana, A., Faour, J.
"Pressure dependence of the effective charge of ionic crystals"
. Journal of Physics and Chemistry of Solids, vol. 45, no. 5, 1984, pp. 571-574.
http://dx.doi.org/10.1016/0022-3697(84)90093-3---------- VANCOUVER ----------
Batana, A., Faour, J. Pressure dependence of the effective charge of ionic crystals. J Phys Chem Solids. 1984;45(5):571-574.
http://dx.doi.org/10.1016/0022-3697(84)90093-3