A simple model is used for dilute polar/nonpolar systems, based on the additivity of electric susceptibilities of a solute/solvent interaction species and a nonpolar solvent. A spherical cavity is considered. Permittivity values, calculated as a function of concentration, are in good agreement with experimental results when the model is applied to systems containing water or lower alcohols in nine nonpolar solvents. © 1982 American Chemical Society.
| Documento: | Artículo |
| Título: | Dielectric properties of binary mixtures. 5. Dilute alcohol/nonpolar solvent systems |
| Autor: | Barón, M.; Mechetti, H. |
| Filiación: | Departamento de Física, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellón 1, 1428 Buenos Aires, Argentina Departamento de Física, Facultad de Ciencias Físicas, Universidad Nacional de San Luis, 5700 San Luis, Argentina |
| Año: | 1982 |
| Volumen: | 86 |
| Número: | 17 |
| Página de inicio: | 3464 |
| Página de fin: | 3468 |
| DOI: | http://dx.doi.org/10.1021/j100214a038 |
| Título revista: | Journal of Physical Chemistry |
| ISSN: | 00223654 |
| PDF: | https://bibliotecadigital.exactas.uba.ar/download/paper/paper_00223654_v86_n17_p3464_Baron.pdf |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223654_v86_n17_p3464_Baron |
