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Abstract:

The oxidation of triphenylphosphine in the presence of various photocatalytic systems (dicyanoanthracene/biphenyl, N-methylquinolinium, triphenylpyrylium, and thiatriphenylpyrylium tetrafluoroborate) was investigated by means of both steady state and laser flash photolysis experiments. The effect of different additives (including 1,4-benzoquinone, diphenylsulfoxide, tetramethylethylene, and sodium azide) on the photosensitized oxidation was investigated in order to fully characterize the involved intermediates. Photoinduced electron transfer and final regeneration of the catalyst occur when dicyanoanthracene and N-methylquinolinium are used, while in cage oxygen transfer to the photoexcited (thio)pyrylium derivatives have been characterized in the last two cases. © 2016 American Chemical Society.

Registro:

Documento: Artículo
Título:Reactive Oxygen Species (ROS)-vs Peroxyl-Mediated Photosensitized Oxidation of Triphenylphosphine: A Comparative Study
Autor:Bonesi, S.M.; Protti, S.; Albini, A.
Filiación:Departamento de Química Orgánica, CIHIDECAR - CONICET, Ciudad Universitaria, FCEyN, University of Buenos Aires, Buenos Aires, 1428, Argentina
Department of Chemistry, PhotoGreen Lab, V.Le Taramelli 12, Pavia, 27100, Italy
Palabras clave:Oxidation; Photolysis; Comparative studies; Laser flash photolysis; Photo-induced electron transfer; Photocatalytic systems; Photosensitized oxidation; Reactive oxygen species; Tetrafluoroborates; Triphenyl phosphines; Reaction intermediates; peroxy radical; photosensitizing agent; reactive oxygen metabolite; triphenylphosphine; Article; chemical structure; electron transport; fluorescence; laser; oxidation; photochemistry; photolysis; photosensitized oxidation; quantum yield; steady state
Año:2016
Volumen:81
Número:23
Página de inicio:11678
Página de fin:11685
DOI: http://dx.doi.org/10.1021/acs.joc.6b02088
Título revista:Journal of Organic Chemistry
Título revista abreviado:J. Org. Chem.
ISSN:00223263
CODEN:JOCEA
CAS:triphenylphosphine, 603-35-0
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v81_n23_p11678_Bonesi

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Citas:

---------- APA ----------
Bonesi, S.M., Protti, S. & Albini, A. (2016) . Reactive Oxygen Species (ROS)-vs Peroxyl-Mediated Photosensitized Oxidation of Triphenylphosphine: A Comparative Study. Journal of Organic Chemistry, 81(23), 11678-11685.
http://dx.doi.org/10.1021/acs.joc.6b02088
---------- CHICAGO ----------
Bonesi, S.M., Protti, S., Albini, A. "Reactive Oxygen Species (ROS)-vs Peroxyl-Mediated Photosensitized Oxidation of Triphenylphosphine: A Comparative Study" . Journal of Organic Chemistry 81, no. 23 (2016) : 11678-11685.
http://dx.doi.org/10.1021/acs.joc.6b02088
---------- MLA ----------
Bonesi, S.M., Protti, S., Albini, A. "Reactive Oxygen Species (ROS)-vs Peroxyl-Mediated Photosensitized Oxidation of Triphenylphosphine: A Comparative Study" . Journal of Organic Chemistry, vol. 81, no. 23, 2016, pp. 11678-11685.
http://dx.doi.org/10.1021/acs.joc.6b02088
---------- VANCOUVER ----------
Bonesi, S.M., Protti, S., Albini, A. Reactive Oxygen Species (ROS)-vs Peroxyl-Mediated Photosensitized Oxidation of Triphenylphosphine: A Comparative Study. J. Org. Chem. 2016;81(23):11678-11685.
http://dx.doi.org/10.1021/acs.joc.6b02088