Abstract:
Lithium dialkylamides react with CO to afford dialkylformamides 2, tetralkylhydroxymalonamides 3, and dialkylglyoxylamides 4. Reaction conditions are described to produce 2 or 4 in good yields. © 1983, American Chemical Society. All rights reserved.
Referencias:
- Presented in part at the 15th Argentine Chemical Symposium (1980), Tucumán; Trzupek, L.S., Newirth, T.L., Kelly, E.G., Nudelman, N.S., Whitesides, G.M., (1973) J. Am. Chem. Soc., 95, p. 8118
- Nudelman, N.S., Vitale, A.A., (1981) Org. Prep. Proc. 1981, 13, 144; J. Org. Chem., 46, p. 4625. , J. Organomet. Chem., in press
- Nudelman, N.S., Outumuro, P., (1982) J. Org. Chem., 47, p. 4347
- Nudelman, N.S., Pérez, D., (1981) An. Asoc. Quim. Argent, 69, p. 195. , For a standard preparation procedure see
- Longhi, P., Montagna, R., Mazzochi, R., (1965) Chim. Ind. (Milan), 47, p. 480
- Jutzi, P., Schroeder, F.W., (1971) Angew. Chem., Int. Ed. Engl., 10, p. 339
- Rautenstrauch, V., Joyeaux, M., (1979) Angew. Chem., Int. Ed. Engl., 18, p. 83
- Fletcher, A.S., Smith, K., Swaminathan, K., (1977) J. Chem. Soc, Perkin Trans. 1, p. 1881
- Schollkopf, V.S., Beckhaus, H., (1976) Angew. Chem. Int. Ed. Engl., 15, p. 293. , Banhidai, B.; Schollkopf, V. S. Angew. Chem. Int. Ed. Engl. 1973, 12, 836
- Tsuda, T., Miwa, M., Saegusa, T., (1979) J. Org. Chem., 44, p. 3734
Citas:
---------- APA ----------
Nudelman, N.S. & Pérez, D.
(1983)
. Insertion of Carbon Monoxide into Lithium-Nitrogen Bonds. One-Pot Synthesis of Dialkylformamides and Dialkylglyoxylamides. Journal of Organic Chemistry, 48(1), 133-134.
http://dx.doi.org/10.1021/jo00149a030---------- CHICAGO ----------
Nudelman, N.S., Pérez, D.
"Insertion of Carbon Monoxide into Lithium-Nitrogen Bonds. One-Pot Synthesis of Dialkylformamides and Dialkylglyoxylamides"
. Journal of Organic Chemistry 48, no. 1
(1983) : 133-134.
http://dx.doi.org/10.1021/jo00149a030---------- MLA ----------
Nudelman, N.S., Pérez, D.
"Insertion of Carbon Monoxide into Lithium-Nitrogen Bonds. One-Pot Synthesis of Dialkylformamides and Dialkylglyoxylamides"
. Journal of Organic Chemistry, vol. 48, no. 1, 1983, pp. 133-134.
http://dx.doi.org/10.1021/jo00149a030---------- VANCOUVER ----------
Nudelman, N.S., Pérez, D. Insertion of Carbon Monoxide into Lithium-Nitrogen Bonds. One-Pot Synthesis of Dialkylformamides and Dialkylglyoxylamides. J. Org. Chem. 1983;48(1):133-134.
http://dx.doi.org/10.1021/jo00149a030