Abstract:
From the reaction of aqueous ammonia with octa-O-acetylcellobionic acid nitrile, 3-O-β-D-glucopyranosyl-1,1-bis(acetamido)-1-deoxy-D-arabitol (I), 3-O-β-D-glucopyranosyl-N-acetyl-D-arabofuranosylanime (II), and 3-O-β-D-glucopyranosyl-D-arabinose (III) were isolated. The hepta-O-acetyl derivative of I was prepared and the acyclic structure of the nitrogenated moiety was established by oxidation with sodium metaperiodate. By methylation of II, subsequent hydrolysis, and isolation of the methyl sugars produced, the presence of a furanose ring in its D-arabinose moiety was demonstrated.
Registro:
Documento: |
Artículo
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Título: | The reaction of ammonia with acylated disaccharides. V. The Wohl reaction with octa-O-acetylcellobionic acid nitrile |
Autor: | Deferrari, J.O.; Gelpi, M.E.; Cadenas, R.A. |
Filiación: | Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
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Idioma: |
Inglés
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Año: | 1965
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Volumen: | 30
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Número: | 7
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Página de inicio: | 2328
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Página de fin: | 2330
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Título revista: | Journal of Organic Chemistry
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ISSN: | 00223263
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v30_n7_p2328_Deferrari |
Citas:
---------- APA ----------
Deferrari, J.O., Gelpi, M.E. & Cadenas, R.A.
(1965)
. The reaction of ammonia with acylated disaccharides. V. The Wohl reaction with octa-O-acetylcellobionic acid nitrile. Journal of Organic Chemistry, 30(7), 2328-2330.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v30_n7_p2328_Deferrari [ ]
---------- CHICAGO ----------
Deferrari, J.O., Gelpi, M.E., Cadenas, R.A.
"The reaction of ammonia with acylated disaccharides. V. The Wohl reaction with octa-O-acetylcellobionic acid nitrile"
. Journal of Organic Chemistry 30, no. 7
(1965) : 2328-2330.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v30_n7_p2328_Deferrari [ ]
---------- MLA ----------
Deferrari, J.O., Gelpi, M.E., Cadenas, R.A.
"The reaction of ammonia with acylated disaccharides. V. The Wohl reaction with octa-O-acetylcellobionic acid nitrile"
. Journal of Organic Chemistry, vol. 30, no. 7, 1965, pp. 2328-2330.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v30_n7_p2328_Deferrari [ ]
---------- VANCOUVER ----------
Deferrari, J.O., Gelpi, M.E., Cadenas, R.A. The reaction of ammonia with acylated disaccharides. V. The Wohl reaction with octa-O-acetylcellobionic acid nitrile. 1965;30(7):2328-2330.
Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v30_n7_p2328_Deferrari [ ]