By means of methylation and hydrolysis techniques it was demonstrated that the 1,1-bis(acetamido)-1-deoxycellobiitol, the 1,1-bis(acetamido)-1-deoxylactitol, and the 1,1-bis(acetamido)-1-deoxymaltitol obtained by the reaction of ammonia upon the corresponding acetylated aldobioses have an acyclic structure in the nitrogenated moiety. The separation of a mixture of 2,3,5,6-tetra-O-methyl-D-glucose and 2,3,4,6-tetra-O-methyl-D-glucose by gas-liquid and by anion-exchange resin chromatographies is described. © 1965, American Chemical Society. All rights reserved.
Documento: | Artículo |
Título: | The Reaction of Ammonia with Acylated Disaccharides. IV. The Structure of the 1,1-Bis(acetamido)-1-deoxyaldobiitols |
Autor: | Deferrari, J.O.; Cadenas, R.A. |
Filiación: | Departamento de Quimica Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina |
Año: | 1965 |
Volumen: | 30 |
Número: | 6 |
Página de inicio: | 2007 |
Página de fin: | 2009 |
DOI: | http://dx.doi.org/10.1021/jo01017a070 |
Título revista: | Journal of Organic Chemistry |
Título revista abreviado: | J. Org. Chem. |
ISSN: | 00223263 |
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v30_n6_p2007_Deferrari |