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Abstract:

A galactomannan composed of 28.6% D-galactose and 71.4% D-mannose was isolated in 30% yield from the seeds of Gleditsia amorphoides. Periodate oxidation showed that all the mannose and galactose units were attacked since hydrolysis of the reduced oxopolysaccharide gave only glycerol (1 mole) and erythritol (2.7 moles). The periodate consumption was 4.8 moles for every four hexose residues and at the same time 1 mole of formic acid was produced. Hydrolysis of the methylated polysaccharide yielded 2,3,4,6-tetra-O-methyl-D-galactose (1 mole), 2,3,6-tri-O-methyl-D-mannose (2.1 moles), and 2,3-di-O-methyl-D-mannose (1.1 moles). © 1965, American Chemical Society. All rights reserved.

Registro:

Documento: Artículo
Título:The Constitution of a Galactomannan from the Seed of Gleditsia amorphoides
Autor:Cerezo, A.S.
Filiación:Departamento de Química Orgánica, Facultad de Ciencias Exactas, Universidad de Buenos Aires, Buenos Aires, Argentina
Año:1965
Volumen:30
Número:3
Página de inicio:924
Página de fin:927
DOI: http://dx.doi.org/10.1021/jo01014a065
Título revista:Journal of Organic Chemistry
Título revista abreviado:J. Org. Chem.
ISSN:00223263
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v30_n3_p924_Cerezo

Citas:

---------- APA ----------
(1965) . The Constitution of a Galactomannan from the Seed of Gleditsia amorphoides. Journal of Organic Chemistry, 30(3), 924-927.
http://dx.doi.org/10.1021/jo01014a065
---------- CHICAGO ----------
Cerezo, A.S. "The Constitution of a Galactomannan from the Seed of Gleditsia amorphoides" . Journal of Organic Chemistry 30, no. 3 (1965) : 924-927.
http://dx.doi.org/10.1021/jo01014a065
---------- MLA ----------
Cerezo, A.S. "The Constitution of a Galactomannan from the Seed of Gleditsia amorphoides" . Journal of Organic Chemistry, vol. 30, no. 3, 1965, pp. 924-927.
http://dx.doi.org/10.1021/jo01014a065
---------- VANCOUVER ----------
Cerezo, A.S. The Constitution of a Galactomannan from the Seed of Gleditsia amorphoides. J. Org. Chem. 1965;30(3):924-927.
http://dx.doi.org/10.1021/jo01014a065