Artículo
Gelpi, M.E.; Deferrari, J.O.; Cadenas, R.A. "The Reaction of Ammonia with Acylated Disaccharides. VII. The Wohl Reaction with Octa-0-acetyllactobiononitrile" (1965) Journal of Organic Chemistry. 30(12):4064-4066
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Abstract:
From the reaction of aqueous ammonia with octa-O-acetyllactobiononitrile, 3-O-(β-D-galactopyranosyl)-D-arabinose, l,l-diacetamido-l-deoxy-3-O-(β-D-galactopyranosyl)-D-arabinitol (I), and N-acetyl-3-0-(β-D-galacto-pyranosyl)-D-arabinofuranosylamine (II) were isolated. The acyclic structure of I was established by periodate oxidation and by formation of a hepta-O-acetyl derivative. By methylation of II, subsequent hydrolysis, and isolation of the methyl sugars produced, the presence of a furanose ring in its D-arabinose moiety was demonstrated. © 1965, American Chemical Society. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | The Reaction of Ammonia with Acylated Disaccharides. VII. The Wohl Reaction with Octa-0-acetyllactobiononitrile |
| Autor: | Gelpi, M.E.; Deferrari, J.O.; Cadenas, R.A. |
| Filiación: | Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina |
| Año: | 1965 |
| Volumen: | 30 |
| Número: | 12 |
| Página de inicio: | 4064 |
| Página de fin: | 4066 |
| DOI: | http://dx.doi.org/10.1021/jo01023a018 |
| Título revista: | Journal of Organic Chemistry |
| Título revista abreviado: | J. Org. Chem. |
| ISSN: | 00223263 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v30_n12_p4064_Gelpi |
Citas:
---------- APA ----------
Gelpi, M.E., Deferrari, J.O. & Cadenas, R.A. (1965) . The Reaction of Ammonia with Acylated Disaccharides. VII. The Wohl Reaction with Octa-0-acetyllactobiononitrile. Journal of Organic Chemistry, 30(12), 4064-4066.http://dx.doi.org/10.1021/jo01023a018
---------- CHICAGO ----------
Gelpi, M.E., Deferrari, J.O., Cadenas, R.A. "The Reaction of Ammonia with Acylated Disaccharides. VII. The Wohl Reaction with Octa-0-acetyllactobiononitrile" . Journal of Organic Chemistry 30, no. 12 (1965) : 4064-4066.http://dx.doi.org/10.1021/jo01023a018
---------- MLA ----------
Gelpi, M.E., Deferrari, J.O., Cadenas, R.A. "The Reaction of Ammonia with Acylated Disaccharides. VII. The Wohl Reaction with Octa-0-acetyllactobiononitrile" . Journal of Organic Chemistry, vol. 30, no. 12, 1965, pp. 4064-4066.http://dx.doi.org/10.1021/jo01023a018
---------- VANCOUVER ----------
Gelpi, M.E., Deferrari, J.O., Cadenas, R.A. The Reaction of Ammonia with Acylated Disaccharides. VII. The Wohl Reaction with Octa-0-acetyllactobiononitrile. J. Org. Chem. 1965;30(12):4064-4066.http://dx.doi.org/10.1021/jo01023a018
