Artículo
Gros, E.G.; Deulofeu, V. "Reaction of Ammonia with Some Acetylated and Benzoylated Monosaccharides. IX. The Migration of Benzoyl Groups in the Ammonolysis of 1,2,3,4,6/Penta-O-benzoyl-D-galactoses" (1964) Journal of Organic Chemistry. 29(12):3647-3654
Consulte la política de Acceso Abierto del editor
Abstract:
By ammonolysis of 1,2,3,4,6/penta-O-benzoyl-d-galaetoses, having labeled benzoyl groups at different carbon atoms, the following contributions of each benzoyl group to the formation of 1, 1/bis(benzamido)/1/deoxy-d-galactitol have been found: C/2, 0.13; C/3, 0.62; C/4, 1.02; C/6, 0.18 moles per mole. Compared with the penta-O-benzoyl-d-glucoses, the most interesting variation is the increase of the contribution of the benzoyl group at C/4, from 0.82 in the d-glucose series to total migration in the D-galactoses, that takes place at the expense of the contribution of the benzoyls in C/3 and C/6. © 1964, American Chemical Society. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | Reaction of Ammonia with Some Acetylated and Benzoylated Monosaccharides. IX. The Migration of Benzoyl Groups in the Ammonolysis of 1,2,3,4,6/Penta-O-benzoyl-D-galactoses |
| Autor: | Gros, E.G.; Deulofeu, V. |
| Filiación: | División de Química Orgánica, Comision Nacional de Energía Atómica, Laboratorio de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Perú 222, Buenos Aires, Argentina |
| Año: | 1964 |
| Volumen: | 29 |
| Número: | 12 |
| Página de inicio: | 3647 |
| Página de fin: | 3654 |
| DOI: | http://dx.doi.org/10.1021/jo01035a054 |
| Título revista: | Journal of Organic Chemistry |
| Título revista abreviado: | J. Org. Chem. |
| ISSN: | 00223263 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v29_n12_p3647_Gros |
Citas:
---------- APA ----------
Gros, E.G. & Deulofeu, V. (1964) . Reaction of Ammonia with Some Acetylated and Benzoylated Monosaccharides. IX. The Migration of Benzoyl Groups in the Ammonolysis of 1,2,3,4,6/Penta-O-benzoyl-D-galactoses. Journal of Organic Chemistry, 29(12), 3647-3654.http://dx.doi.org/10.1021/jo01035a054
---------- CHICAGO ----------
Gros, E.G., Deulofeu, V. "Reaction of Ammonia with Some Acetylated and Benzoylated Monosaccharides. IX. The Migration of Benzoyl Groups in the Ammonolysis of 1,2,3,4,6/Penta-O-benzoyl-D-galactoses" . Journal of Organic Chemistry 29, no. 12 (1964) : 3647-3654.http://dx.doi.org/10.1021/jo01035a054
---------- MLA ----------
Gros, E.G., Deulofeu, V. "Reaction of Ammonia with Some Acetylated and Benzoylated Monosaccharides. IX. The Migration of Benzoyl Groups in the Ammonolysis of 1,2,3,4,6/Penta-O-benzoyl-D-galactoses" . Journal of Organic Chemistry, vol. 29, no. 12, 1964, pp. 3647-3654.http://dx.doi.org/10.1021/jo01035a054
---------- VANCOUVER ----------
Gros, E.G., Deulofeu, V. Reaction of Ammonia with Some Acetylated and Benzoylated Monosaccharides. IX. The Migration of Benzoyl Groups in the Ammonolysis of 1,2,3,4,6/Penta-O-benzoyl-D-galactoses. J. Org. Chem. 1964;29(12):3647-3654.http://dx.doi.org/10.1021/jo01035a054
