The reaction of methanolic ammonia with α-octa-O-acetylcellobiose is described. From the reaction were isolated cellobiose, N,N′-diacetylcellobiosylidenediamine, and a hepta-O-acetyl-N-acetylcellobiosylamine which is considered the alpha anomer of the product already described as hepta-O-acetyl-N-acetylcellobiosylamine. The acetyl derivative of N,N′-diacetylcellobiosylidenediamine was prepared and the influence of solvent upon the reaction studied is discussed. © 1963, American Chemical Society. All rights reserved.
| Documento: | Artículo |
| Título: | The Reaction of Ammonia with Acylated Disaccharides. I. Acetyl Derivatives of Cellobiose |
| Autor: | Deferrari, J.O.; Cadenas, R.A. |
| Filiación: | Laboratorio de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Argentina |
| Año: | 1963 |
| Volumen: | 28 |
| Número: | 4 |
| Página de inicio: | 1070 |
| Página de fin: | 1072 |
| DOI: | http://dx.doi.org/10.1021/jo01039a049 |
| Título revista: | Journal of Organic Chemistry |
| Título revista abreviado: | J. Org. Chem. |
| ISSN: | 00223263 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v28_n4_p1070_Deferrari |