1. By the action of methanolic ammonia on the α- and β-isomers of pentabenzoyl-d-glucose, d-glucose dibenzamide is obtained in almost the same yield. 2. When hexaacetyl-d-gluco-d-ido-heptonic nitrile is treated with methanolic ammonia, N-acetyl-d-glucofuranosylamine is produced, in a yield similar to that obtained from the epimer, hexaacetyl-d-gluco-d-gulo-heptonic nitrile. 3. A discussion is given of the mechanism of the reaction. © 1952, American Chemical Society. All rights reserved.
Documento: | Artículo |
Título: | The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation |
Autor: | Deulofeu, V.; Deferrari, J.O. |
Filiación: | Laboratorio de Química Orgánica, Facultad de Ciencias Exactas, Físicas y Naturales, Laboratorio de Química Biológica, Facultad de Ciencias Médicas, Buenos Aires, Argentina |
Año: | 1952 |
Volumen: | 17 |
Número: | 8 |
Página de inicio: | 1087 |
Página de fin: | 1092 |
DOI: | http://dx.doi.org/10.1021/jo50008a003 |
Título revista: | Journal of Organic Chemistry |
Título revista abreviado: | J. Org. Chem. |
ISSN: | 00223263 |
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v17_n8_p1087_Deulofeu |