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Abstract:

The title proton transfer complex was isolated from the reaction of CuCl 2 ·2H 2 O with pyridine-2,6-dicarboxylic acid (dipic-H 2 ) in presence of 3-amino-1-propanol (PA) under reflux condition. It was thoroughly characterized by FAB-mass, FT-IR, electronic (ligand field), EPR spectroscopic and X-ray crystallographic techniques. The complex crystallizes in the space group C1c1 of the monoclinic system. The unit cell parameters are, a = 17.247(5), b = 20.058(5) Å, c = 15.320(4) Å and β = 109.235(5)°. Extensive H-bonding between the complex anion [Cu(dipic) 2 ] 2- and the surrounding cations [PA-H] + results in a 3D network, supported with additional π-π interactions of the ligand (dipic) 2- neighboring units. The SOD mimic activity of the present complex was also examined using NBT assay. © 2012 Elsevier B.V. All rights reserved.

Registro:

Documento: Artículo
Título:H-bonded supramolecular assembly via proton transfer: Isolation, X-ray crystallographic characterization and SOD mimic activity of [Cu(dipic) 2 ] 2 [PA-H] 4 ·5H 2 O
Autor:Siddiqi, Z.A.; Khalid, M.; Shahid, M.; Kumar, S.; Sharma, P.K.; Siddique, A.; Anjuli
Filiación:Coordination Chemistry Research Group, Department of Chemistry, Aligarh Muslim University, Aligarh 202 002, India
DQIAQF/INQUIMAE, Universidad de Buenos Aires, Ciudad Universitaria, Pab. II, p. 3, EHA1428 Buenos Aires, Argentina
Palabras clave:π-π Interactions; 3D network; Crystal structure; H-bonding; Proton transfer complex; SOD mimic activity; 3 amino 1 propanols; 3D networks; Complex anions; Crystallographic characterization; FAB-MASS; H-bonded; H-bonding; Ligand field; Monoclinic systems; Pyridine-2 ,6-dicarboxylic acid; Reflux conditions; Space Groups; Supramolecular assemblies; Unit cell parameters; Copper compounds; Crystal structure; Electron spin resonance spectroscopy; Ligands; Proton transfer; Three dimensional computer graphics; X ray crystallography; Hydrogen bonds
Año:2013
Volumen:1033
Página de inicio:98
Página de fin:103
DOI: http://dx.doi.org/10.1016/j.molstruc.2012.08.029
Título revista:Journal of Molecular Structure
Título revista abreviado:J. Mol. Struct.
ISSN:00222860
CODEN:JMOSB
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00222860_v1033_n_p98_Siddiqi

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Citas:

---------- APA ----------
Siddiqi, Z.A., Khalid, M., Shahid, M., Kumar, S., Sharma, P.K., Siddique, A. & Anjuli (2013) . H-bonded supramolecular assembly via proton transfer: Isolation, X-ray crystallographic characterization and SOD mimic activity of [Cu(dipic) 2 ] 2 [PA-H] 4 ·5H 2 O. Journal of Molecular Structure, 1033, 98-103.
http://dx.doi.org/10.1016/j.molstruc.2012.08.029
---------- CHICAGO ----------
Siddiqi, Z.A., Khalid, M., Shahid, M., Kumar, S., Sharma, P.K., Siddique, A., et al. "H-bonded supramolecular assembly via proton transfer: Isolation, X-ray crystallographic characterization and SOD mimic activity of [Cu(dipic) 2 ] 2 [PA-H] 4 ·5H 2 O" . Journal of Molecular Structure 1033 (2013) : 98-103.
http://dx.doi.org/10.1016/j.molstruc.2012.08.029
---------- MLA ----------
Siddiqi, Z.A., Khalid, M., Shahid, M., Kumar, S., Sharma, P.K., Siddique, A., et al. "H-bonded supramolecular assembly via proton transfer: Isolation, X-ray crystallographic characterization and SOD mimic activity of [Cu(dipic) 2 ] 2 [PA-H] 4 ·5H 2 O" . Journal of Molecular Structure, vol. 1033, 2013, pp. 98-103.
http://dx.doi.org/10.1016/j.molstruc.2012.08.029
---------- VANCOUVER ----------
Siddiqi, Z.A., Khalid, M., Shahid, M., Kumar, S., Sharma, P.K., Siddique, A., et al. H-bonded supramolecular assembly via proton transfer: Isolation, X-ray crystallographic characterization and SOD mimic activity of [Cu(dipic) 2 ] 2 [PA-H] 4 ·5H 2 O. J. Mol. Struct. 2013;1033:98-103.
http://dx.doi.org/10.1016/j.molstruc.2012.08.029