Artículo
Abstract:
Electronic spectra (absorption, fluorescence and phosphorescence emission spectra) of chlorocarbazoles 1a-e, 2a-b, 3a, 4a-b, 5a, 6a, 7a, 8a-c, 9a and 9b in acetonitrile and in solid matrix have been recorded at 298 and 77 K. The dynamic properties of the lowest excited singlet and triplet states in term of fluorescence and phosphorescence lifetime, τf and τp, fluorescence and phosphorescence quantum yield, φf and φp have been measured in the same experimental conditions and from these data the radiative and the radiationless rate constants (kf0, kisc, kf0(77), kisc(77), kp0 and knr0) and the intersystem crossing quantum yield, φisc, were derived. The intramolecular heavy atom effect (HAE) on the spectroscopic data and photophysical rate constant was analyzed and the incorporation of chlorine atoms to the carbazole moiety proved their ability to quench the fluorescence emission by spin-orbital coupling. The values of the HOMO and LUMO energy, the oscillator strength (f) and the λmax(abs) associated to the electronic transitions, the heat of formation of the chlorocarbazoles and the corresponding radical cation (ΔHf and ΔHf(RC)) and the adiabatic ionization potential (Ia) were also calculated by using the semiempirical PM3 method after HF/3-21G geometrical optimization, and were compared with the spectroscopic and photophysical data as well as with the one electron oxidation potential data (Ep/2). © 2002 Elsevier Science B.V. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | Electronic spectroscopy of N- and C-substituted chlorocarbazoles in homogeneous media and in solid matrix |
| Autor: | Bonesi, S.M.; Erra-Balsells, R. |
| Filiación: | Departamento De Química Orgánica, Facultad De Ciencias Exactas Y Naturales, Universidad De Buenos Aires, c.c.74-suc. 30, 1430 Buenos Aires, Argentina |
| Palabras clave: | Chlorocarbazoles; Electronic spectra at 298 K; Electronic spectra at 77 K; PM3 chlorocarbazole electronic spectra calculation; PM3 chlorocarbazole molecular orbital calculations; Absorption spectroscopy; Electron energy levels; Electron transitions; Fluorescence; Phosphorescence; Positive ions; Rate constants; Chlorocarbazoles; Heavy atom effect (HAE); Aromatic hydrocarbons |
| Año: | 2002 |
| Volumen: | 97 |
| Número: | 2 |
| Página de inicio: | 83 |
| Página de fin: | 101 |
| DOI: | http://dx.doi.org/10.1016/S0022-2313(01)00240-X |
| Título revista: | Journal of Luminescence |
| Título revista abreviado: | J Lumin |
| ISSN: | 00222313 |
| CODEN: | JLUMA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00222313_v97_n2_p83_Bonesi |
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Citas:
---------- APA ----------
Bonesi, S.M. & Erra-Balsells, R. (2002) . Electronic spectroscopy of N- and C-substituted chlorocarbazoles in homogeneous media and in solid matrix. Journal of Luminescence, 97(2), 83-101.http://dx.doi.org/10.1016/S0022-2313(01)00240-X
---------- CHICAGO ----------
Bonesi, S.M., Erra-Balsells, R. "Electronic spectroscopy of N- and C-substituted chlorocarbazoles in homogeneous media and in solid matrix" . Journal of Luminescence 97, no. 2 (2002) : 83-101.http://dx.doi.org/10.1016/S0022-2313(01)00240-X
---------- MLA ----------
Bonesi, S.M., Erra-Balsells, R. "Electronic spectroscopy of N- and C-substituted chlorocarbazoles in homogeneous media and in solid matrix" . Journal of Luminescence, vol. 97, no. 2, 2002, pp. 83-101.http://dx.doi.org/10.1016/S0022-2313(01)00240-X
---------- VANCOUVER ----------
Bonesi, S.M., Erra-Balsells, R. Electronic spectroscopy of N- and C-substituted chlorocarbazoles in homogeneous media and in solid matrix. J Lumin. 2002;97(2):83-101.http://dx.doi.org/10.1016/S0022-2313(01)00240-X
