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Abstract:

Absorption, emission, and anisotropy measurements were performed on poly-[2-methoxy-5(2′-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) and poly-(9,9′-dioctylfluorene-2,7-diyl) (PF) solutions of various solvents, and in thin films deposited from them. The good correlation of MEH-PPV absorption and emission energy with Hildebrandt's dispersive parameter indicate that dispersive forces regulate the effective extent of the luminophore. The excitation and the emission spectra of α and β chains can be distinguished in PF solutions using the steady-state anisotropy. PF films show greater memory effect from the solutions from which they were spun than MEH-PPV. Anisotropy of MEH-PPV is very low, both in solutions and in films reflecting efficient energy migration. Anisotropy of PF in solutions and films demonstrates great differences in energy transfer efficiency within the α and β phases, while there is no energy transfer between these chain conformations. © 2009.

Registro:

Documento: Artículo
Título:Study of solvent-conjugated polymer interactions by polarized spectroscopy: MEH-PPV and Poly(9,9′-dioctylfluorene-2,7-diyl)
Autor:Cossiello, R.F.; Susman, M.D.; Aramendía, P.F.; Atvars, T.D.Z.
Filiación:Universidade Estadual de Campinas, Instituto de Química, Caixa Postal 6154, Campinas, 13084-971 SP, Brazil
INQUIMAE, Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Pabellon 2, Ciudad Universitaria, C1428EHA Buenos Aires, Argentina
Palabras clave:Conjugated polymers; Fluorescence anisotropy; MEH-PPV; Polyfluorene; Solutions and films; Solvent effects; Fluorescence anisotropy; MEH-PPV; Polyfluorene; Polyfluorene solutions; Solvent effects; Absorption; Anisotropy; Conjugated polymers; Emission spectroscopy; Energy transfer; Fluorescence; Polymers; Solvents; Solution mining
Año:2010
Volumen:130
Número:3
Página de inicio:415
Página de fin:423
DOI: http://dx.doi.org/10.1016/j.jlumin.2009.10.006
Título revista:Journal of Luminescence
Título revista abreviado:J Lumin
ISSN:00222313
CODEN:JLUMA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00222313_v130_n3_p415_Cossiello

Referencias:

  • Miyate, S., Nalva, H.S., (1998) Organic Electroluminescent Materials and Devices
  • Burroughes, J.H., Bradley, D.D.C., Brown, A.R., Marks, R.N., Mackay, K., Friend, R.H., Burns, P.L., Holmes., A.B., (1990) Nature, 347 (6293), p. 539
  • Akcelrud., L., (2003) Prog. Polym. Sci., 28 (6), p. 875
  • Machado, A.M., Neto, J.D.D., Cossiello, R.F., Atvars, T.D.Z., Ding, L., Karasz, F.E., Akcelrud, L., (2005) Polymer, 46 (8), p. 2452
  • Machado, A.M., Munaro, M., Martins, T.D., Davila, L.Y.A., Giro, R., Caldas, M.J., Atvars, T.D.Z., Akcelrud, L.C., (2006) Macromolecules, 39 (9), p. 3398
  • Yang, S.H., Lee., C.F.J., (2007) Optoelectron. Adv. Mater., 9 (4), p. 2078
  • Chang, L.H., Lee, Y.D., Chen, C.T., (2006) Macromolecules, 39 (9), p. 3262
  • Zhang, H.A., Li, Y., Jinag, Q., Xie, M.G., Peng, J.B., Cao., Y., (2007) J. Mater. Sci., 42 (12), p. 4476
  • Ramey, M.B., Hiller, J.A., Rubner, M.F., Tan, C.Y., Schanze, K.S., Reynolds, J.R., (2005) Macromolecules, 38 (2), p. 234
  • Gu, Z., Bao, Y.-J., Zhang, Y., Wang, M., Shen, Q.-D., (2006) Macromolecules, 39 (9), p. 3125
  • Nesterov, E.E., Zhu, Z.G., Swager., T.M., (2005) J. Am. Chem. Soc., 127 (25), p. 10083
  • Gruber, J., Li, R.W.C., Aguiar, L.H.J.M.C., Garcia, T.L., Oliveira, H.P.M., Atvars, T.D.Z., Nogueira., A.F., (2006) Synth. Met., 156 (24), p. 104
  • (2008) Polyfluorenes Adv. Polym. Sci., 212. , Scherf U., and Neher D. (Eds), Springer-Verlag, Berlin
  • Scherf, U., List., E.J.W., (2002) Adv. Mater., 14 (7), p. 477
  • Kawase, T., Shimoda, T., Newsome, C., Sirringhaus, H., Friend., R.H., (2003) Thin Solid Films., 438, p. 279
  • Gurel, E.E., Pang, Y., Karasz., F.E., (2002) Thin Solid Films., 417 (1-2), p. 147
  • Amrutha, S.R., Jayakannan., M.J., (2006) Phys. Chem. B, 110 (9), p. 4083
  • Deans, R., Kim, J., Machacek, M.R., Swager., T.M., (2000) J. Am. Chem. Soc., 122 (35), p. 8565
  • McQuade, D.T., Kim, J., Swager., T.M., (2000) J. Am. Chem. Soc., 122 (24), p. 5885
  • Schwartz., B.J., (2003) Ann. Rev. Phys. Chem., 54, p. 141
  • Zyung, T., Jung, S.D., Hwang., D.H., (2001) Synth. Met., 117 (1-3), p. 223
  • Lee, S., Lee, J.Y., Lee., H., (1999) Synth. Met., 101 (1-3), p. 248
  • Nguyen, T.Q., Yee, R.Y., Schwartz., B.J., (2001) J. Photochem. Photobiol. A: Chem., 144 (1), p. 21
  • Nguyen, T.Q., Schwartz, B.J., Schaller, R.D., Johnson, J.C., Lee, L.F., Haber, L.H., Saykally., R.J., (2001) J. Phys. Chem. B, 105 (22), p. 5153
  • Schaller, R.D., Lee, L.F., Johnson, J.C., Haber, L.H., Saykally, R.J., Vieceli, J., Benjamin, I., Schwartz., B.J., (2002) J. Phys. Chem. B, 106 (37), p. 9496
  • Jeng, U., Hsu, C.H., Sheu, H.S., Lee, H.Y., Inigo, A.R., Chiu, H.C., Fann, W.S., Chen, S.A., (2005) Macromolecules, 38 (15), p. 6566
  • Yang, C.Y., Hide, F., Díaz-García, M.A., Heeger, A.J., Cao, Y., (1998) Polymer, 39 (11), p. 2299
  • Teetsov, J., Bout., D.A.V., (2000) J. Phys. Chem. B, 104 (40), p. 9378
  • McNeill, C.R., Frohne, H., Holdsworth, J.L., Dastoor., P.C., (2004) Nano Lett., 4 (12), p. 2503
  • Cimrova, V., Neher., D., (1996) Synth. Met., 76 (1-3), p. 125
  • Nguyen, T.Q., Doan, V., Schwartz., B.J., (1999) J. Chem. Phys., 110 (8), p. 4068
  • Kim, D.Y., Grey, J.K., Barbara., P.F., (2006) Synth. Met., 156 (2-4), p. 336
  • Huser, T., Yan, M., (2001) J. Photochem. Photobiol. A: Chem, 144 (1), p. 43
  • Sartori, S.S., De Feyter, S., Hofkens, J., Van der Auweraer, M., De Schryver, F., Brunner, K., Hofstraat, J.W., (2003) Macromolecules, 36 (2), p. 500
  • Chen, S.H., Su, A.C., Huang, Y.F., Su, C.H., Peng, G.Y., Chen, S.A., (2002) Macromolecules, 35 (11), p. 4229
  • Soutar, I., Jones, C., Lucas, D.M., Swanson., L., (1996) J. Photochem. Photobiol. A: Chem., 102 (1), p. 87
  • Gaab, K.M., Bardeen., C.J., (2004) J. Phys. Chem. A, 108 (49), p. 10801
  • Synak, A., Gondek, G., Bojarski, P., Kulak, L., Kubicki, A., Szabelski, M., Kwiek., P., (2004) Chem. Phys. Lett., 399 (1-3), p. 114
  • Hennecke, M., Damerau, T., Müllen, K., (1993) Macromolecules, 26 (13), p. 3411
  • Herz, L.M., Phillips., R.T., (2000) Phys. Rev., 61 (20), p. 13691
  • Dias, F.B., Maçanita, A.L., Melo, J.S., Burrows, H.D., Günter, R., Scherf, U., Monkman., A.P., (2003) J. Chem. Phys., 39 (15), p. 7119
  • Dias, F.B., Morgado, J., Maçanita, A.L., Costa, P.C., Burrows, H.D., Monkman, A.P., (2006) Macromolecules, 39 (17), p. 5854
  • Grell, M., Bradley, D.D.C., Ungar, G., Hill, J., Whitehead, K.S., (1999) Macromolecules, 32 (18), p. 5810
  • Cadby, A.J., Lane, P.A., Mellor, H., Martin, S.J., Grell, M., Giebeler, C., Bradley, D.D.C., Vardeny., Z.V., (2000) Phys. Rev. B, 62 (23), p. 15604
  • Vaughan, H.L., Dias, F.M.B., Monkman., A.P., (2005) J. Chem. Phys., 122 (1), p. 014902
  • Cossiello, R.F., Akcelrud, L., Atvars., T.D.Z., Braz., J., (2005) Chem. Soc., 16 (1), p. 74
  • Fytas, G., Nothofer, H.G., Scherf, U., Vlassopoulos, D., Meier, G., (2002) Macromolecules, 35 (2), p. 481
  • Winnik., M.L., (1986) Photophysical and Photochemical Tools in Polymer Science, 182. , D. Riedel, New York
  • Halary, J.L., Monnerie., L., (1986) Photophysical and Photochemical Tools in Polymer Science, 182. , D. Riedel, New York p. 589
  • Hansen., M.H., (1969) Ind. Eng. Chem. Prod. Res. Dev., 8, p. 2
  • Barton, A.F.M., (1983) Handbook of Solubility Parameters and Other Cohesion Parameters, , CRC Press, Boca Raton, Florida p. 232
  • Barton., A.F.M., (1975) Chem. Rev., 75 (6), p. 731
  • Brandrup, J., Immergut, E.H., Grulke, E.A., (1993) Polymer Handbook. Fourth ed., , Academic Press, New York p. 2336
  • Grage, M.M.L., Wood, P.W., Ruseckas, A., Pullerits, T., Mitchell, W., Burn, P.L., Samuel, I.D.W., Sundstrom., V., (2003) J. Chem. Phys., 118 (16), p. 7644
  • Collison, C.J., Rothberg, L.J., Treemaneekarn, V., Li, Y., (2001) Macromolecules, 34 (7), p. 2346
  • Lemmer, U., Heun, S., Mahrt, R.F., Scherf, U., Hopmeier, M., Siegner, U., Gobel, E.O., Bässler., H., (1995) Chem. Phys. Lett., 240 (4), p. 373
  • Lakowicz, J.R., (1999) Principles of Fluorescence Spectroscopy, , Academic Press, New York
  • Chen, S.H., Su, A.C., Su, C.H., Chen, S.A., (2005) Macromolecules, 38 (2), p. 379
  • Chen, S.H., Chou, H.L., Su, A.C., Chen, S.A., (2004) Macromolecules, 37 (18), p. 6833
  • Winokur, M.J., Slinker, J., Huber., D.L., (2003) Phys. Rev. B, 67 (18), p. 184106
  • Müller, J.G., Atas, E., Tan, C., Schanze, K.S., Kleiman., V.D., (2006) J. Am. Chem. Soc., 128 (12), p. 4007
  • Marushchak, D., Johansson., L.B.A., (2005) J. Fluorescence, 15 (5), p. 797
  • Azuma, H., Asada, K., Kobayashi, T., Naito., H., (2006) Thin Solid Films, 509 (1-2), p. 182
  • Tang, H.Z., Fujiki, M., Motonaga, M., (2002) Polymer, 43 (23), p. 6213
  • Traiphol, R., Charoenthai, N., Srikhirin, T., Kerdcharoen, T., Osotchan, T., Maturos, T., (2007) Polymer, 48 (3), p. 813
  • Narwark, O., Meskers, S.C.J., Peetz, R., Thorn-Csányi, E., Bässler., H., (2003) Chem. Phys., 294 (1), p. 1
  • Quan, S., Teng, F., Xu, Z., Qian, L., Hou, Y., Wang, Y., Xu., X., (2006) Eur. Polym. J., 42 (1), p. 228
  • Traiphol, R., Sanguansat, P., Srikhirin, T., Kerdcharoen, T., Osotchan, T., (2006) Macromolecules, 42 (20), p. 1165

Citas:

---------- APA ----------
Cossiello, R.F., Susman, M.D., Aramendía, P.F. & Atvars, T.D.Z. (2010) . Study of solvent-conjugated polymer interactions by polarized spectroscopy: MEH-PPV and Poly(9,9′-dioctylfluorene-2,7-diyl). Journal of Luminescence, 130(3), 415-423.
http://dx.doi.org/10.1016/j.jlumin.2009.10.006
---------- CHICAGO ----------
Cossiello, R.F., Susman, M.D., Aramendía, P.F., Atvars, T.D.Z. "Study of solvent-conjugated polymer interactions by polarized spectroscopy: MEH-PPV and Poly(9,9′-dioctylfluorene-2,7-diyl)" . Journal of Luminescence 130, no. 3 (2010) : 415-423.
http://dx.doi.org/10.1016/j.jlumin.2009.10.006
---------- MLA ----------
Cossiello, R.F., Susman, M.D., Aramendía, P.F., Atvars, T.D.Z. "Study of solvent-conjugated polymer interactions by polarized spectroscopy: MEH-PPV and Poly(9,9′-dioctylfluorene-2,7-diyl)" . Journal of Luminescence, vol. 130, no. 3, 2010, pp. 415-423.
http://dx.doi.org/10.1016/j.jlumin.2009.10.006
---------- VANCOUVER ----------
Cossiello, R.F., Susman, M.D., Aramendía, P.F., Atvars, T.D.Z. Study of solvent-conjugated polymer interactions by polarized spectroscopy: MEH-PPV and Poly(9,9′-dioctylfluorene-2,7-diyl). J Lumin. 2010;130(3):415-423.
http://dx.doi.org/10.1016/j.jlumin.2009.10.006