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Ancilotto, F.; Cole, M.W.; Grosman, A.; Hernández, E.S.; Toigo, F. "Expansion or contraction of slit pores due to gas uptake" (2011) Journal of Low Temperature Physics. 163(5-6):284-301
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Abstract:

Adsorption inside a slit pore of flexible width w is explored, with a focus on how w varies as a function of the external pressure P of a gas in equilibrium with the adsorbate within the pore. The analysis is first carried out in general, using a minimization of the thermodynamic grand potential energy of the system. This leads to an equation predicting both the gas uptake N as a function of chemical potential μ and the expansion (or contraction) of the pore in response to the adsorbate's pressure. The resulting equilibrium behavior depends on the elastic parameters of the host material. Explicit results are derived for three adsorption systems: a low density fluid, Ar (a classical fluid at finite temperature T) in a graphite pore and 4He within a Au pore at T=0. The resulting behaviors include some situations where the pore expands and others for which it contracts. The difference arises from the sign of the thermodynamic response of the fluid as a function of slit width. © 2011 Springer Science+Business Media, LLC.

Registro:

Documento: Artículo
Título:Expansion or contraction of slit pores due to gas uptake
Autor:Ancilotto, F.; Cole, M.W.; Grosman, A.; Hernández, E.S.; Toigo, F.
Filiación:Department of Physics, University of Padua, via Marzolo 8, Padua, Italy
Department of Physics, Penn State University, University Park, PA 16802, United States
Institut des NanoSciences de Paris, Université Pierre et Marie Curie, UMR7588, 4 Place Jussieu, Paris 75005, France
Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, and Consejo Nacional de Investigaciones Cientificas y Tecnicas, Buenos Aires 1428, Argentina
Palabras clave:Capillary condensation; Imbibition; Physisorption in pores; Adsorption system; Capillary condensation; Classical fluids; Elastic parameters; Equilibrium behavior; External pressures; Finite temperatures; Gas uptake; Host materials; Imbibition; IT contracts; Low-density fluids; Slit pores; Slit width; Adsorbates; Fluids; Physisorption; Behavioral research
Año:2011
Volumen:163
Número:5-6
Página de inicio:284
Página de fin:301
DOI: http://dx.doi.org/10.1007/s10909-011-0350-4
Título revista:Journal of Low Temperature Physics
Título revista abreviado:J. Low Temp. Phys.
ISSN:00222291
CODEN:JLTPA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00222291_v163_n5-6_p284_Ancilotto

Referencias:

  • Serre, C., Millange, F., Thouvenot, C., Nogues, M., Marsolier, G., Louer, D., Ferey, G., Very large breathing effect in the first nanoporous chromium(III)-based solids: MIL-53 or CrIII(OH)·{O 2C-C 6H 4- CO 2}·{HO 2C-C 6H 4 -CO 2H} x·H 2O y (2002) Journal of the American Chemical Society, 124 (45), pp. 13519-13526. , DOI 10.1021/ja0276974
  • Ferey, G., Latroche, M., Serre, C., Millange, F., Loiseau, T., Percheron-Guegan, A., (2003) Chem. Commun., 24, p. 2976. , 10.1039/b308903g
  • Kondo, A., Noguchi, H., Ohnishi, S., Kajiro, H., Tohdoh, A., Hattori, Y., Xu, W.-C., Kaneko, K., Novel expansion/shrinkage modulation of 2D layered MOF triggered by clathrate formation with CO 2 molecules (2006) Nano Letters, 6 (11), pp. 2581-2584. , DOI 10.1021/nl062032b
  • Culp, J.T., Smith, M.R., Bittner, E., Bockrath, B., (2008) J. Am. Chem. Soc., 130, p. 112427. , 10.1021/ja802474b
  • Fletcher, A.J., Thomas, K.M., Rosseinsky, M.J., Flexibility in metal-organic framework materials: Impact on sorption properties (2005) Journal of Solid State Chemistry, 178 (8 SPEC. ISS.), pp. 2491-2510. , DOI 10.1016/j.jssc.2005.05.019, PII S0022459605002185
  • Li, D., Kaneko, K., Hydrogen bond-regulated microporous nature of copper complex-assembled microcrystals (2001) Chemical Physics Letters, 335 (1-2), pp. 50-56. , DOI 10.1016/S0009-2614(00)01419-6, PII S0009261400014196
  • Kitaura, R., Seki, K., Akiyama, G., Kitagawa, S., Porous coordination-polymer crystals with gated channels specific for supercritical gases (2003) Angewandte Chemie - International Edition, 42 (4), pp. 428-431. , DOI 10.1002/anie.200390130
  • Culp, J.T., Smith, M.R., Bittner, E., Bockrath, B., (2008) J. Am. Chem. Soc., 130, p. 12427. , 10.1021/ja802474b
  • Zhao, X., Xiao, B., Fletcher, A.J., Thomas, K.M., Bradshaw, D., Rosseinsky, M.J., Hysteretic adsorption and desorption of hydrogen by nanoporous metal-organic frameworks (2004) Science, 306 (5698), pp. 1012-1015. , DOI 10.1126/science.1101982
  • Gelb, L.D., Gubbins, K.E., Radhakrishnan, R., Sliwinska-Bartkowiak, M., (1999) Rep. Prog. Phys., 62, p. 1573. , 10.1088/0034-4885/62/12/201 1999RPPh.62.1573G
  • Noa, K.E., Lueking, A.D., Cole, M.W., (2010) J. Low Temp. Phys., , 10.1007/s10909-010-0337-6
  • Bangham, D.H., Fakhoury, N., (1930) Proc. R. Soc. Lond. Ser. A, Math. Phys. Sci., 130, p. 81. , 10.1098/rspa.1930.0189 1930RSPSA.130.81B
  • Wiig, E.O., (1949) J. Am. Chem. Soc., 71, p. 561. , 10.1021/ja01170a051
  • Amberg, C.H., McIntosh, R., (1952) Can. J. Chem., 30, p. 1012. , 10.1139/v52-121
  • Quinn, H.W., McIntosh, R., (1957) Can. J. Chem., 35, p. 745. , 10.1139/v57-106
  • Dash, J.G., Suzanne, H., Schechter, H., Peierls, R.E., (1976) Surf. Sci., 60, p. 411. , 10.1016/0039-6028(76)90325-3 1976SurSc.60.411D
  • Reichenauer, G., Scherer, G.W., Extracting the pore size distribution of compliant materials from nitrogen adsorption (2001) Colloids and Surfaces A: Physicochemical and Engineering Aspects, 187-188, pp. 41-50. , DOI 10.1016/S0927-7757(01)00619-7, PII S0927775701006197
  • Herman, T., Day, J., Beamish, J., Deformation of silica aerogel during fluid adsorption (2006) Physical Review B - Condensed Matter and Materials Physics, 73 (9), pp. 1-7. , http://oai.aps.org/oai?verb=GetRecord&Identifier=oai:aps.org: PhysRevB.73.094127&metadataPrefix=oai_apsmeta_2, DOI 10.1103/PhysRevB.73.094127, 094127
  • Dolino, G., Bellet, D., Faivre, C., (1996) Phys. Rev. B, 54, p. 17919. , 10.1103/PhysRevB.54.17919 1996PhRvB.5417919D
  • Dourdain, S., Britton, D.T., Reichert, H., Gibaud, A., (2008) Appl. Phys. Lett., 93, p. 183108. , 10.1063/1.2996412 2008ApPhL.93r3108D
  • M.P. Rossi, Y. Gogotsi, K.G. Kornev, 25, 2804 (2009); Günther, G., Prass, J., Paris, O., Schoen, M., (2008) Phys. Rev. Lett., 101, p. 86104. , 10.1103/PhysRevLett.101.086104
  • Grosman, A., Ortega, C., (2008) Phys. Rev. B, 78, p. 085433. , 10.1103/PhysRevB.78.085433 2008PhRvB.78h5433G
  • Kim, H.-Y., Gatica, S.M., Stan, G., Cole, M.W., (2009) J. Low Temp. Phys., 156, p. 1. , 10.1007/s10909-009-9884-0 2009JLTP.156.1K
  • Günther, G., Schoen, M., (2009) Phys. Chem. Chem. Phys., 11, p. 9082. , 10.1039/b903514a
  • Schoen, M., Paris, O., Günther, G., Müter, D., Prass, J., Fratzl, P., (2010) Phys. Chem. Chem. Phys., 12, p. 11267. , 10.1039/c000782j
  • Grosman, A., Ortega, C., (2009) Langmuir, 25, p. 8083. , 10.1021/la9005955
  • Grosman, A., Ortega, C., (2010) Appl. Surf. Sci., 256, p. 5210. , 10.1016/j.apsusc.2009.12.098 2010ApSS.256.5210G
  • Balbuena, P.B., Berry, D., Gubbins, K.E., (1993) J. Phys. Chem., 97, p. 937. , 10.1021/j100106a021
  • Ustinov, E.A., Do, D.D., Effect of adsorption deformation on thermodynamic characteristics of a fluid in slit pores at sub-critical conditions (2006) Carbon, 44 (13), pp. 2652-2663. , DOI 10.1016/j.carbon.2006.04.015, PII S0008622306002107
  • Ancilotto, F., Toigo, F., (1999) Phys. Rev. B, 60, p. 9019. , 10.1103/PhysRevB.60.9019 1999PhRvB.60.9019A
  • Mistura, G., Ancilotto, F., Bruschi, L., Toigo, F., (1999) Phys. Rev. Lett., 82, p. 795. , 10.1103/PhysRevLett.82.795 1999PhRvL.82.795M
  • Gatica, S.M., Calbi, M.M., Cole, M.W., Simple model of capillary condensation in porous media (2002) Physical Review E - Statistical, Nonlinear, and Soft Matter Physics, 65 (6), pp. 061605/1-061605/4. , http://scitation.aip.org/getpdf/servlet/GetPDFServlet?filetype= pdf&id=PLEEE8000065000006061605000001&idtype=cvips, DOI 10.1103/PhysRevE.65.061605, 061605
  • Trasca, R.A., Calbi, M.M., Cole, M.W., Ricardo, J.L., (2004) Phys. Rev. E, 69, p. 011605. , 10.1103/PhysRevE.69.011605 2004PhRvE.69a1605T
  • Wang, Q., Johnson, K.I.J., (1998) Int. J. Thermophys., 19, p. 835. , 10.1023/A:1022690922778
  • Evans, R., Bettolo Marconi, U.M., Tarazona, P., (1986) J. Chem. Soc. Faraday Trans. i, 82, p. 1763
  • Morishige, K., Fujii, H., Uga, M., Kinukawa, D., (1997) Langmuir, 13, p. 3494. , 10.1021/la970079u
  • Bruch, L.W., Cole, M.W., Zaremba, E., (2007) Physical Adsorption: Forces and Phenomena, , Dover Mineola
  • Dalfovo, F., Lastri, A., Pricaupenko, L., Stringari, S., Treiner, J., (1995) Phys. Rev. B, 52, p. 1193. , 10.1103/PhysRevB.52.1193 1995PhRvB.52.1193D
  • Hernández, E.S., Cole, M.W., Boninsegni, M., (2003) Phys. Rev. B, 68, p. 1254181. , 10.1103/PhysRevB.68.125418
  • Hernández, E.S., (2004) J. Low Temp. Phys., 137, p. 89. , 10.1023/B:JOLT.0000044236.08782.91 2004JLTP.137.89H
  • Parsegian, V.A., (2008) Van der Waals Forces, , Cambridge University Press Cambridge
  • Dzyaloshinskii, I.E., Lifshitz, E.M., Pitaevskii, L.P., (1961) Adv. Phys., 10, p. 165. , 10.1080/00018736100101281 1961AdPhy.10.165D 128930

Citas:

---------- APA ----------
Ancilotto, F., Cole, M.W., Grosman, A., Hernández, E.S. & Toigo, F. (2011) . Expansion or contraction of slit pores due to gas uptake. Journal of Low Temperature Physics, 163(5-6), 284-301.
http://dx.doi.org/10.1007/s10909-011-0350-4
---------- CHICAGO ----------
Ancilotto, F., Cole, M.W., Grosman, A., Hernández, E.S., Toigo, F. "Expansion or contraction of slit pores due to gas uptake" . Journal of Low Temperature Physics 163, no. 5-6 (2011) : 284-301.
http://dx.doi.org/10.1007/s10909-011-0350-4
---------- MLA ----------
Ancilotto, F., Cole, M.W., Grosman, A., Hernández, E.S., Toigo, F. "Expansion or contraction of slit pores due to gas uptake" . Journal of Low Temperature Physics, vol. 163, no. 5-6, 2011, pp. 284-301.
http://dx.doi.org/10.1007/s10909-011-0350-4
---------- VANCOUVER ----------
Ancilotto, F., Cole, M.W., Grosman, A., Hernández, E.S., Toigo, F. Expansion or contraction of slit pores due to gas uptake. J. Low Temp. Phys. 2011;163(5-6):284-301.
http://dx.doi.org/10.1007/s10909-011-0350-4