Several new palladium (II) complexes containing co-ordinated sulphato groups are reported. Infra-red spectral data has been applied to the characterization of the compounds. The spectrum of Pd(NH3)SO4·H2O indicates the presence of unidentate sulphato groups, whereas those of [Pd(NH3)2SO4] and PdSO4 are considered to be consistent with polymeric structures involving bridging sulphato groups. Chemical and infra-red spectral evidence suggest that the complexes [PdphenSO4], Pdpy2SO4·H2O, [Pd(DMSO)2SO4] and PdSO4·2H2O involve chelating sulphato groups. © 1966.
| Documento: | Artículo |
| Título: | Sulphato complexes of palladium (II) |
| Autor: | Eskenazi, R.; Raskovan, J.; Levitus, R. |
| Filiación: | Facultad de Ciencias Exactas y Naturales, Perú, 222 Buenos Aires, Argentina |
| Año: | 1966 |
| Volumen: | 28 |
| Número: | 2 |
| Página de inicio: | 521 |
| Página de fin: | 526 |
| DOI: | http://dx.doi.org/10.1016/0022-1902(66)80333-0 |
| Título revista: | Journal of Inorganic and Nuclear Chemistry |
| ISSN: | 00221902 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00221902_v28_n2_p521_Eskenazi |
