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Abstract:

Nucleophilic trifluoromethylation and perfluoroalkylation reactions have been the outstanding approach during the last few decades to effect fluoroalkyl group addition or substitution reactions. In most instances, perfluoroalkyl-metal species participate at the beginning of the reactions. In this account, however, the latest nucleophilic non-metal assisted or uncatalyzed trifluoromethylation and perfluoroalkylation reactions of substrates bearing biological relevance will be discussed. © 2014 Elsevier B.V.

Registro:

Documento: Artículo
Título:Nucleophilic non-metal assisted trifluoromethylation and perfluoroalkylation reactions of organic substrates
Autor:Barata-Vallejo, S.; Torviso, M.R.; Lantaño, B.; Bonesi, S.M.; Postigo, A.
Filiación:Departamento de Química Orgánica, Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Junín 954, Buenos Aires CP 1113, Argentina
Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires CP 1428, Argentina
Palabras clave:Fluorinated sulfides; Fluorinated sulfones; Fluorinated sulfoxides; Fluoroform; Nucleophilic trifluoromethylation; Trimethylsilyltrifluoromethane
Año:2014
Volumen:161
Página de inicio:134
Página de fin:141
DOI: http://dx.doi.org/10.1016/j.jfluchem.2014.01.016
Título revista:Journal of Fluorine Chemistry
Título revista abreviado:J. Fluor. Chem.
ISSN:00221139
CODEN:JFLCA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00221139_v161_n_p134_BarataVallejo

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Citas:

---------- APA ----------
Barata-Vallejo, S., Torviso, M.R., Lantaño, B., Bonesi, S.M. & Postigo, A. (2014) . Nucleophilic non-metal assisted trifluoromethylation and perfluoroalkylation reactions of organic substrates. Journal of Fluorine Chemistry, 161, 134-141.
http://dx.doi.org/10.1016/j.jfluchem.2014.01.016
---------- CHICAGO ----------
Barata-Vallejo, S., Torviso, M.R., Lantaño, B., Bonesi, S.M., Postigo, A. "Nucleophilic non-metal assisted trifluoromethylation and perfluoroalkylation reactions of organic substrates" . Journal of Fluorine Chemistry 161 (2014) : 134-141.
http://dx.doi.org/10.1016/j.jfluchem.2014.01.016
---------- MLA ----------
Barata-Vallejo, S., Torviso, M.R., Lantaño, B., Bonesi, S.M., Postigo, A. "Nucleophilic non-metal assisted trifluoromethylation and perfluoroalkylation reactions of organic substrates" . Journal of Fluorine Chemistry, vol. 161, 2014, pp. 134-141.
http://dx.doi.org/10.1016/j.jfluchem.2014.01.016
---------- VANCOUVER ----------
Barata-Vallejo, S., Torviso, M.R., Lantaño, B., Bonesi, S.M., Postigo, A. Nucleophilic non-metal assisted trifluoromethylation and perfluoroalkylation reactions of organic substrates. J. Fluor. Chem. 2014;161:134-141.
http://dx.doi.org/10.1016/j.jfluchem.2014.01.016