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Vazquez, M.V.; de Sanchez, S.R.; Calvo, E.J.; Schiffrin, D.J. "The electrochemical reduction of oxygen on polycrystalline copper in borax buffer" (1994) Journal of Electroanalytical Chemistry. 374(1-2):189-197
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Abstract:

Oxygen reduction proceeds on copper electrodes in boric + borate buffer by the four electron pathway. Difference reflectance spectroscope shows that surface oxide species are formed during oxygen reduction on pre-reduced copper. The redox couple Cu2O/CuO plays an important role in the reduction sequence and a CE mechanism is proposed, although direct electron transfer to the oxygen molecule from oxide-free surfaces appears possible. In this case, the behaviour of copper is similar to that of the isoelectronic metal gold. © 1994.

Registro:

Documento: Artículo
Título:The electrochemical reduction of oxygen on polycrystalline copper in borax buffer
Autor:Vazquez, M.V.; de Sanchez, S.R.; Calvo, E.J.; Schiffrin, D.J.
Filiación:INTEMA, Facultad de Ingeniería, Universidad Nacional de Mar del Plata, 7600 Mar del Plata, Argentina
INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Buenos Aires, Pab. II, Ciudad Universitaria, 1428 Buenos Aires, Argentina
Chemistry Department, University of Liverpool, Liverpool, L69 3BX, United Kingdom
Año:1994
Volumen:374
Número:1-2
Página de inicio:189
Página de fin:197
DOI: http://dx.doi.org/10.1016/0022-0728(94)03343-9
Título revista:Journal of Electroanalytical Chemistry
Título revista abreviado:J Electroanal Chem
ISSN:00220728
CODEN:JECHE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00220728_v374_n1-2_p189_Vazquez

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Citas:

---------- APA ----------
Vazquez, M.V., de Sanchez, S.R., Calvo, E.J. & Schiffrin, D.J. (1994) . The electrochemical reduction of oxygen on polycrystalline copper in borax buffer. Journal of Electroanalytical Chemistry, 374(1-2), 189-197.
http://dx.doi.org/10.1016/0022-0728(94)03343-9
---------- CHICAGO ----------
Vazquez, M.V., de Sanchez, S.R., Calvo, E.J., Schiffrin, D.J. "The electrochemical reduction of oxygen on polycrystalline copper in borax buffer" . Journal of Electroanalytical Chemistry 374, no. 1-2 (1994) : 189-197.
http://dx.doi.org/10.1016/0022-0728(94)03343-9
---------- MLA ----------
Vazquez, M.V., de Sanchez, S.R., Calvo, E.J., Schiffrin, D.J. "The electrochemical reduction of oxygen on polycrystalline copper in borax buffer" . Journal of Electroanalytical Chemistry, vol. 374, no. 1-2, 1994, pp. 189-197.
http://dx.doi.org/10.1016/0022-0728(94)03343-9
---------- VANCOUVER ----------
Vazquez, M.V., de Sanchez, S.R., Calvo, E.J., Schiffrin, D.J. The electrochemical reduction of oxygen on polycrystalline copper in borax buffer. J Electroanal Chem. 1994;374(1-2):189-197.
http://dx.doi.org/10.1016/0022-0728(94)03343-9