Artículo

Peinetti, A.S.; Mizrahi, M.; Requejo, F.G.; Buceta, D.; López-Quintela, M.A.; González, G.A.; Battaglini, F. "Synthesis of nickel entities: From highly stable zerovalent nanoclusters to nanowires. Growth control and catalytic behavior" (2018) Journal of Colloid and Interface Science. 516:371-378
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Abstract:

Non-noble metal nanoclusters synthesis is receiving increased attention due to their unique catalytic properties and lower cost. Herein, the synthesis of ligand-free Ni nanoclusters with an average diameter of 0.7 nm corresponding to a structure of 13 atoms is presented; they exhibit a zero-valence state and a high stability toward oxidation and thermal treatment. The nanoclusters formation method consists in the electroreduction of nickel ions inside an ordered mesoporous alumina; also, by increasing the current density, other structures can be obtained reaching to nanowires of 10 nm diameter. A seed-mediated mechanism is proposed to explain the growth to nanowires inside these mesoporous cavities. The size dependence on the catalytic behavior of these entities is illustrated by studying the reduction of methylene blue where the nanoclusters show an outstanding performance. © 2018 Elsevier Inc.

Registro:

Documento: Artículo
Título:Synthesis of nickel entities: From highly stable zerovalent nanoclusters to nanowires. Growth control and catalytic behavior
Autor:Peinetti, A.S.; Mizrahi, M.; Requejo, F.G.; Buceta, D.; López-Quintela, M.A.; González, G.A.; Battaglini, F.
Filiación:INQUIMAE (CONICET), Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, C1428EHA, Argentina
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas, INIFTA (CONICET y Dto. Química, Fac. Cs Ex, UNLP), La Plata, 1900, Argentina
Laboratory of Magnetism and Nanotechnology, Technological Research Institute, University of Santiago de Compostela, Santiago de Compostela, E-15782, Spain
Palabras clave:Catalytic methylene blue reduction; EXAFS and XANES characterization; Growth mechanism; Nickel nanoclusters; Nickel nanowires; Zero-valence nickel; Alumina; Aromatic compounds; Chelation; Electrolytic reduction; Nanowires; Nickel; Precious metals; Growth mechanisms; Methylene Blue; Nickel nanowires; Nickel-nanoclusters; XANES; Nanoclusters; methylene blue; nanowire; nickel; Article; catalysis; catalyst; current density; growth regulation; oxidation; priority journal; reduction (chemistry); scanning electron microscopy; structure analysis; synthesis
Año:2018
Volumen:516
Página de inicio:371
Página de fin:378
DOI: http://dx.doi.org/10.1016/j.jcis.2018.01.083
Título revista:Journal of Colloid and Interface Science
Título revista abreviado:J. Colloid Interface Sci.
ISSN:00219797
CODEN:JCISA
CAS:methylene blue, 61-73-4; nickel, 7440-02-0
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219797_v516_n_p371_Peinetti

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Citas:

---------- APA ----------
Peinetti, A.S., Mizrahi, M., Requejo, F.G., Buceta, D., López-Quintela, M.A., González, G.A. & Battaglini, F. (2018) . Synthesis of nickel entities: From highly stable zerovalent nanoclusters to nanowires. Growth control and catalytic behavior. Journal of Colloid and Interface Science, 516, 371-378.
http://dx.doi.org/10.1016/j.jcis.2018.01.083
---------- CHICAGO ----------
Peinetti, A.S., Mizrahi, M., Requejo, F.G., Buceta, D., López-Quintela, M.A., González, G.A., et al. "Synthesis of nickel entities: From highly stable zerovalent nanoclusters to nanowires. Growth control and catalytic behavior" . Journal of Colloid and Interface Science 516 (2018) : 371-378.
http://dx.doi.org/10.1016/j.jcis.2018.01.083
---------- MLA ----------
Peinetti, A.S., Mizrahi, M., Requejo, F.G., Buceta, D., López-Quintela, M.A., González, G.A., et al. "Synthesis of nickel entities: From highly stable zerovalent nanoclusters to nanowires. Growth control and catalytic behavior" . Journal of Colloid and Interface Science, vol. 516, 2018, pp. 371-378.
http://dx.doi.org/10.1016/j.jcis.2018.01.083
---------- VANCOUVER ----------
Peinetti, A.S., Mizrahi, M., Requejo, F.G., Buceta, D., López-Quintela, M.A., González, G.A., et al. Synthesis of nickel entities: From highly stable zerovalent nanoclusters to nanowires. Growth control and catalytic behavior. J. Colloid Interface Sci. 2018;516:371-378.
http://dx.doi.org/10.1016/j.jcis.2018.01.083