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Bordoni, A.V.; Lombardo, M.V.; Regazzoni, A.E.; Soler-Illia, G.J.A.A.; Wolosiuk, A. "Simple thiol-ene click chemistry modification of SBA-15 silica pores with carboxylic acids" (2015) Journal of Colloid and Interface Science. 450:316-324
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Abstract:

A straightforward approach for anchoring tailored carboxylic groups in mesoporous SiO2 colloidal materials is presented. The thiol-ene photochemical reaction between vinyltrimethoxysilane precursors and various thiocarboxylic acids which has, click chemistry features (i.e. high conversion yields, insensitivity to oxygen, mild reaction conditions), results in carboxylated silane precursors that can be readily used as surface modifiers. The carboxylic groups of acetic, undecanoic and succinic acid were immobilized on the silica mesopore walls of SBA-15 powders employing the synthesized silane precursors. Post-grafting has been confirmed through infrared spectrometry (FTIR), energy dispersive X-ray spectroscopy (EDS), elemental analysis (EA) and zeta potential measurements. Detailed field-emission gun scanning electron microscopy (FESEM) images and small angle X-ray scattering (SAXS) data revealed parallel mesopores and ordered mesostructures. It is shown that the immobilized COOH groups are chemically accessible for acid-base reactions as well as copper adsorption. Immobilization of easily synthesized tailored carboxylic modified alkoxide precursors within mesoporous systems provides a unique chemical nanoenvironment within these ordered frameworks. © 2015 Elsevier Inc.

Registro:

Documento: Artículo
Título:Simple thiol-ene click chemistry modification of SBA-15 silica pores with carboxylic acids
Autor:Bordoni, A.V.; Lombardo, M.V.; Regazzoni, A.E.; Soler-Illia, G.J.A.A.; Wolosiuk, A.
Filiación:Gerencia Química - Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499 B1650KNA San Martín, Buenos Aires, Argentina
DQIAyQF, FCEN, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón II, Buenos Aires, C1428EHA, Argentina
Palabras clave:Carboxylic groups; Click chemistry; Functionalized SiO2; Mesostructured materials; SBA-15; Thiol-ene addition; Energy dispersive spectroscopy; Fourier transform infrared spectroscopy; Infrared spectroscopy; Mesoporous materials; Photochemical reactions; Scanning electron microscopy; Silica; Synthesis (chemical); X ray scattering; X ray spectroscopy; Carboxylic group; Click chemistry; Functionalized; Mesostructured materials; SBA-15; Thiol-ene additions; Functional groups; carboxylic acid; copper; functional group; oxygen; silane; silane derivative; silicon dioxide; succinic acid; thiol derivative; thiol ene; unclassified drug; undecanoic acid; acid base balance; adsorption; Article; carboxylation; chemical modification; chemical reaction kinetics; chemical structure; click chemistry; colloid; field emission scanning electron microscopy; immobilization; infrared spectrometry; photochemistry; porosity; precursor; priority journal; roentgen spectroscopy; surface property; synthesis; X ray crystallography; zeta potential
Año:2015
Volumen:450
Página de inicio:316
Página de fin:324
DOI: http://dx.doi.org/10.1016/j.jcis.2015.03.030
Título revista:Journal of Colloid and Interface Science
Título revista abreviado:J. Colloid Interface Sci.
ISSN:00219797
CODEN:JCISA
CAS:copper, 15158-11-9, 7440-50-8; oxygen, 7782-44-7; silane, 7803-62-5; silicon dioxide, 10279-57-9, 14464-46-1, 14808-60-7, 15468-32-3, 60676-86-0, 7631-86-9; succinic acid, 110-15-6; thiol derivative, 13940-21-1; undecanoic acid, 112-37-8, 23815-71-6
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219797_v450_n_p316_Bordoni

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Citas:

---------- APA ----------
Bordoni, A.V., Lombardo, M.V., Regazzoni, A.E., Soler-Illia, G.J.A.A. & Wolosiuk, A. (2015) . Simple thiol-ene click chemistry modification of SBA-15 silica pores with carboxylic acids. Journal of Colloid and Interface Science, 450, 316-324.
http://dx.doi.org/10.1016/j.jcis.2015.03.030
---------- CHICAGO ----------
Bordoni, A.V., Lombardo, M.V., Regazzoni, A.E., Soler-Illia, G.J.A.A., Wolosiuk, A. "Simple thiol-ene click chemistry modification of SBA-15 silica pores with carboxylic acids" . Journal of Colloid and Interface Science 450 (2015) : 316-324.
http://dx.doi.org/10.1016/j.jcis.2015.03.030
---------- MLA ----------
Bordoni, A.V., Lombardo, M.V., Regazzoni, A.E., Soler-Illia, G.J.A.A., Wolosiuk, A. "Simple thiol-ene click chemistry modification of SBA-15 silica pores with carboxylic acids" . Journal of Colloid and Interface Science, vol. 450, 2015, pp. 316-324.
http://dx.doi.org/10.1016/j.jcis.2015.03.030
---------- VANCOUVER ----------
Bordoni, A.V., Lombardo, M.V., Regazzoni, A.E., Soler-Illia, G.J.A.A., Wolosiuk, A. Simple thiol-ene click chemistry modification of SBA-15 silica pores with carboxylic acids. J. Colloid Interface Sci. 2015;450:316-324.
http://dx.doi.org/10.1016/j.jcis.2015.03.030