Navegar

Colección

Datos Estadísticas

Artículo

La versión final de este artículo es de uso interno. El editor solo permite incluir en el repositorio el artículo en su versión post-print. Por favor, si usted la posee enviela a
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

The binding of proton and metal cations to humic substances has been analyzed with a regularized fitting procedure (using the CONTIN software package) to extract conditional affinity distributions, valid at a given ionic strength, from binding (titration) curves. The procedure was previously tested with simulated titration curves using a simple bi-Gaussian model, the NICA-Donnan model, and the Stockholm humic model. Application to literature data for proton binding shows that in several cases the affinity distribution found is bimodal (carboxylic and phenolic sites) as usually assumed; however in other cases, specially for fulvic acids, a trimodal distribution is clearly discerned, with a smaller peak between the two noted above attributed to the presence of vicinal carboxylic groups. The analysis of metal binding curves has been performed in a few cases where the available data could be reliably processed, separating the proton affinity distribution and obtaining the conditional affinity spectra. For Cd(II) and Pb(II) a bimodal distribution is found, attributed in principle to mono- and bidentate binding, based on spectroscopic data. In the case of Cu(II), a more complex affinity distribution is found showing 3-4 peaks; this is consistent with spectroscopic studies, where different binding modes, up to tetradentate, have been observed. © 2009 Elsevier Inc. All rights reserved.

Registro:

Documento: Artículo
Título:Application of a constrained regularization method to extraction of affinity distributions: Proton and metal binding to humic substances
Autor:Orsetti, S.; Andrade, E.M.; Molina, F.V.
Filiación:INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellon II, Buenos Aires C1428EHA, Argentina
Palabras clave:Binding equilibrium; CONTIN; Humic substances; Pollutant retention; Soil organic matter; Binding equilibrium; CONTIN; Humic substances; Pollutant retention; Soil organic matter; Binding energy; Biogeochemistry; Biological materials; Curve fitting; Ionic strength; Metal recovery; Organic acids; Organic pollutants; Phenols; Protons; Soils; Spectroscopic analysis; Titration; Waste incineration; Binding sites; carboxylic acid; fulvic acid; lead; phenol; proton; article; binding affinity; computer program; computer simulation; constrained regularization method; humic substance; ionic strength; metal binding; methodology; normal distribution; priority journal; reliability; spectroscopy; statistical model; validation process
Año:2009
Volumen:336
Número:2
Página de inicio:377
Página de fin:387
DOI: http://dx.doi.org/10.1016/j.jcis.2009.04.049
Título revista:Journal of Colloid and Interface Science
Título revista abreviado:J. Colloid Interface Sci.
ISSN:00219797
CODEN:JCISA
CAS:fulvic acid, 479-66-3; lead, 7439-92-1; phenol, 108-95-2, 3229-70-7; proton, 12408-02-5, 12586-59-3
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219797_v336_n2_p377_Orsetti

Referencias:

  • Senesi, N., Loffredo, E., (1998) Soil Physical Chemistry. second ed., , Sparks D.L. (Ed), CRC Press, Boca Raton, FL (Chapter 6)
  • Baldock, J.A., Nelson, P.N., (1999) Handbook of Soil Science, pp. B75-B84. , Sumner M.L. (Ed), CRC Press, Boca Raton, FL
  • Milne, C.J., Kinniburgh, D.G., van Riemsdijk, W.H., Tipping, E., (2003) Environ. Sci. Technol., 37, pp. 958-971
  • Smith, E.J., Rey-Castro, C., Longworth, H., Lofts, S., Lawlor, A.J., Tipping, E., (2004) Eur. J. Soil Sci., 55, pp. 433-447
  • Manunza, B., Deiana, S., Maddau, V., Gessa, C., Seeber, R., (1995) Soil Sci. Soc. Am. J., 59, pp. 1570-1574
  • Kinniburgh, D., Van Riemsdijk, W., Koopal, L., Borkovec, M., Benedetti, M., Avena, M., (1999) Colloids Surf. A, 151, pp. 147-166
  • Christl, I., Milne, C.J., Kinniburgh, D.G., Kretzschmar, R., (2001) Environ. Sci. Technol., 35, pp. 2512-2517
  • Leenheer, J., Brown, G., Maccarthy, P., Cabaniss, S., (1998) Environ. Sci. Technol., 32, pp. 2410-2416
  • Senesi, N., Calderoni, G., (1988) Org. Geochem., 13, pp. 1145-1152
  • Sohn, M., Hughes, M., (1981) Geochim. Cosmochim. Acta, 45, pp. 2393-2399
  • Golonka, I., Czechowski, F., Jezierski, A., (2005) Geoderma, 127, pp. 237-252
  • Koper, G., Borkovec, M., (2001) J. Phys. Chem. B, 105, pp. 6666-6674
  • Yamashita, Y., Jaffé, R., (2008) Environ. Sci. Technol., 42, pp. 7374-7379
  • Milne, C.J., Kinniburgh, D.G., Tipping, E., (2001) Environ. Sci. Technol., 35, pp. 2049-2059
  • Fernández, J.M., Plaza, C., Senesi, N., Polo, A., (2007) Chemosphere, 69, pp. 630-635
  • Companys, E., Puy, J., Galceran, J., (2007) Environ. Chem., 4, pp. 347-354
  • Gondar, D., López, R., Fiol, S., Antelo, J., Arce, F., (2006) Geoderma, 135, pp. 196-203
  • Chakraborty, P., Chakrabarti, C., (2008) Water Air Soil Pollut., 195, pp. 63-71
  • Plaza, C., D'Orazio, V., Senesi, N., (2005) Geoderma, 125, pp. 177-186
  • Baker, H., Khalili, F., (2005) Anal. Chim. Acta, 542, pp. 240-248
  • Kinniburgh, D.G., Milne, C.J., Benedetti, M.F., Pinheiro, J.P., Filius, J., Koopal, L.K., Van Riemsdijk, W.H., (1996) Environ. Sci. Technol., 30, pp. 1687-1698
  • Tipping, E., (1994) Comput. Geosci., 20, pp. 973-1023
  • Tipping, E., Berggren, D., Mulder, J., Woof, C., (1995) Eur. J. Soil Sci., 46, pp. 77-94
  • Tipping, E., (1998) Aq. Geochem., 4, pp. 3-48
  • Tipping, E., Lofts, S., Lawlor, A., (1998) Sci. Total Environ., 210-211, pp. 63-77
  • Gustafsson, J.P., (2001) J. Colloid Interface Sci., 244, pp. 102-112
  • Gustafsson, J., Pechova, P., Berggren, D., (2003) Environ. Sci. Technol., 37, pp. 2767-2774
  • Gustafsson, J., Kleja, D., (2005) Environ. Sci. Technol., 39, pp. 5372-5377
  • Gustafsson, J., Persson, I., Kleja, D., Van Schaik, J., (2007) Environ. Sci. Technol., 41, pp. 1232-1237
  • Khai, N., Öborn, I., Hillier, S., Gustafsson, J., (2008) Chemosphere, 70, pp. 1338-1346
  • Puy, J., Galceran, J., Huidobro, C., Companys, E., Samper, N., Garcés, J., Mas, F., (2008) Environ. Sci. Technol., 42, pp. 9289-9295
  • da Silva, J., Tauler, R., (2006) Appl. Spectrosc., 60, pp. 1315-1321
  • Garces, J.L., Mas, F., Puy, J., (2004) J. Chem. Phys., 120, pp. 9266-9276
  • Nederlof, M.M., Van Riemsdijk, W.H., Koopal, L.K., (1992) Environ. Sci. Technol., 26, pp. 763-771
  • Černík, M., Borkovec, M., Westall, J., (1995) Environ. Sci. Technol., 29, pp. 413-425
  • Borkovec, M., Rusch, U., Černík, M., Koper, G., Westall, J., (1996) Colloids Surf. A, 107, pp. 285-296
  • Koopal, L.K., Vos, C.H.W., (1993) Langmuir, 9, pp. 2593-2605
  • Rusch, U., Borkovec, M., Daicic, J., Van Riemsdijk, W., (1997) J. Colloid Interface Sci., 191, pp. 247-255
  • Garces, J.L., Mas, F., Puy, J., (1998) Environ. Sci. Technol., 32, pp. 539-548
  • Bersillon, J., Villieras, F., Bardot, F., Gorner, T., Cases, J., (2001) J. Colloid Interface Sci., 240, pp. 400-411
  • Provencher, S., (1982) Comput. Phys. Commun., 27, pp. 213-227
  • Provencher, S., (1982) Comput. Phys. Commun., 27, pp. 229-242
  • Mao, R., Tang, J., Swanson, B., (2000) J. Food Sci., 65, pp. 374-381
  • Ruf, H., Gould, B., Haase, W., (2000) Langmuir, 16, pp. 471-480
  • Rasteiro, M., Lemos, C., Vasquez, A., (2008) Particul. Sci. Technol., 26, pp. 413-437
  • Morris, K., Cutak, B., Dixon, A., Larive, C., (1999) Anal. Chem., 71, pp. 5315-5321
  • Eberhardt, T., Elder, T., Labbé, N., (2007) J. Wood Chem. Technol., 27, pp. 35-47
  • Putman, B., Van Der Meeren, P., Vanderdeelen, J., (1997) Part. Part. Syst. Char., 14, pp. 73-78
  • Cao, H., Dai, G., Yuan, J., Jean, Y., (1997) Mater. Sci. Forum, 255-257, pp. 238-242
  • Kowalczyk, P., Terzyk, A., Gauden, P., (2002) Langmuir, 18, pp. 5406-5413
  • Puziy, A., Poddubnaya, O., Ritter, J., Ebner, A., Holland, C., (2001) Carbon, 39, pp. 2313-2324
  • Kowalczyk, P., Terzyk, A., Gauden, P., Gun'ko, V., Solarz, L., (2002) J. Colloid Interface Sci., 256, pp. 378-395
  • Haber-Pohlmeier, S., Pohlmeier, A., (1997) J. Colloid Interface Sci., 188, pp. 377-386
  • Puziy, A., Matynia, T., Gawdzik, B., Poddubnaya, O., (1999) Langmuir, 15, pp. 6016-6025
  • Garcés, J.L., Mas, F., Puy, J., (2006) J. Chem. Phys., 124, pp. 044710-044714
  • Karlsson, T., Persson, P., Skyllberg, U., (2006) Environ. Sci. Technol., 40, pp. 2623-2628
  • Zhang, J., Dai, J., Wang, R., Li, F., Wang, W., (2009) Colloids Surf. A, 335, pp. 194-201
  • Kinniburgh, D., Survey, Keyworth, Nottinghamshire (1993) FIT User Guide-Technical Report, , WD/93/23, British Geological, UK
  • Benedetti, M.F., Milne, C.J., Kinniburgh, D.G., Van Riemsdijk, W.H., Koopal, L.K., (1995) Environ. Sci. Technol., 29, pp. 446-457
  • Ruf, H., (2000) Prog. Colloid Polym. Sci., 115, pp. 255-258
  • Celi, L., Schnitzer, M., Nègre, M., (1997) Soil Sci., 162, pp. 189-197
  • Ikeya, K., Yamamoto, S., Watanabe, A., (2004) Org. Geochem., 35, pp. 583-594
  • Polvillo, O., González-Pérez, J., Boski, T., González-Vila, F., (2009) Org. Geochem., 40, pp. 20-28
  • Farmer, V.C., Pisaniello, D.L., (1985) Nature, 313, pp. 474-475
  • Hatcher, P.G., Minard, R.D., (1995) Org. Geochem., 23, pp. 991-994
  • Otto, W., Burton, S., Robert Carper, W., Larive, C., (2001) Environ. Sci. Technol., 35, pp. 4900-4904
  • Otto, W., Robert Carper, W., Larive, C., (2001) Environ. Sci. Technol., 35, pp. 1463-1468
  • Liu, A., Gonzalez, R., (2000) Langmuir, 16, pp. 3902-3909
  • Pommery, J., Ebenga, J., Imbenotte, M., Palavit, G., Erb, F., (1988) Water Res., 22, pp. 185-189
  • Maes, A., Van Herreweghen, E., Van Elewijck, F., Cremers, A., (1992) Sci. Total Environ., 117-118, pp. 463-473
  • Oste, L.A., Temminghoff, E.J.M., Lexmond, T.M., Van Riemsdijk, W.H., (2002) Anal. Chem., 74, pp. 856-862
  • Karlsson, T., Persson, P., Skyllberg, U., (2005) Environ. Sci. Technol., 39, pp. 3048-3055
  • Shi, Z., Allen, H., Di Toro, D., Lee, S., Flores Meza, D., Lofts, S., (2007) Chemosphere, 69, pp. 605-612
  • Grassi, M., Daquino, V., (2005) Ann. Chim., 95, pp. 579-591
  • Cardoza, L., Korir, A., Otto, W., Wurrey, C., Larive, C., (2004) Prog. Nucl. Mag. Res. Sp., 45, pp. 209-238
  • Xia, K., Bleam, W., Helmke, P.A., (1997) Geochim. Cosmochim. Acta, 61, pp. 2211-2221
  • Šenkýř, J., Ročáková, A., Fetsch, D., Havel, J., (1999) Toxicol. Environ. Chem., 68, pp. 377-391
  • Filella, M., Town, R., (2001) Anal. Bioanal. Chem., 370, pp. 413-418
  • Abate, G., Masini, J., (2002) Org. Geochem., 33, pp. 1171-1182
  • Christl, I., Metzger, A., Heidmann, I., Kretzschmar, R., (2005) Environ. Sci. Technol., 39, pp. 5319-5326
  • Lamelas, C., Wilkinson, K., Slaveykova, V., (2005) Environ. Sci. Technol., 39, pp. 6109-6116
  • Fasfous, I., Chakrabarti, C., Murimboh, J., Yapici, T., (2006) Environ. Chem., 3, pp. 276-285
  • Orsetti, S., de las Mercedes Quiroga, M., Andrade, E., (2006) Chemosphere, 65, pp. 2313-2321
  • Alvarez-Puebla, R., Valenzuela-Calahorro, C., Garrido, J., (2004) J. Colloid Interface Sci., 277, pp. 55-61
  • Plaza, C., Senesi, N., García-Gil, J., Polo, A., (2005) Chemosphere, 61, pp. 711-716
  • Hernández, D., Plaza, C., Senesi, N., Polo, A., (2007) Eur. J. Soil Sci., 58, pp. 900-908
  • Alvarez-Puebla, R., Valenzuela-Calahorro, C., Garrido, J., (2004) J. Colloid Interface Sci., 270, pp. 47-55

Citas:

---------- APA ----------
Orsetti, S., Andrade, E.M. & Molina, F.V. (2009) . Application of a constrained regularization method to extraction of affinity distributions: Proton and metal binding to humic substances. Journal of Colloid and Interface Science, 336(2), 377-387.
http://dx.doi.org/10.1016/j.jcis.2009.04.049
---------- CHICAGO ----------
Orsetti, S., Andrade, E.M., Molina, F.V. "Application of a constrained regularization method to extraction of affinity distributions: Proton and metal binding to humic substances" . Journal of Colloid and Interface Science 336, no. 2 (2009) : 377-387.
http://dx.doi.org/10.1016/j.jcis.2009.04.049
---------- MLA ----------
Orsetti, S., Andrade, E.M., Molina, F.V. "Application of a constrained regularization method to extraction of affinity distributions: Proton and metal binding to humic substances" . Journal of Colloid and Interface Science, vol. 336, no. 2, 2009, pp. 377-387.
http://dx.doi.org/10.1016/j.jcis.2009.04.049
---------- VANCOUVER ----------
Orsetti, S., Andrade, E.M., Molina, F.V. Application of a constrained regularization method to extraction of affinity distributions: Proton and metal binding to humic substances. J. Colloid Interface Sci. 2009;336(2):377-387.
http://dx.doi.org/10.1016/j.jcis.2009.04.049