Artículo
Kukuljan, J.A.; Méndez De Leo, L.P.; Alvarez, J.L.; Bianchi, H.L.; Fernández-Prini, R.J. "Volumetric properties of (4-methylphenol + NaOH) at high temperatures" (2003) Journal of Chemical Thermodynamics. 35(9):1541-1552
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Abstract:
The densities of aqueous solutions of 4-methylphenol and its mixtures with sodium hydroxide were measured as a function of concentration at T = 298 K at atmospheric pressure, and between the temperatures 373 K and 463 K at a pressure of 2 MPa. The partial molar volume at infinite dilution of 4-methylphenol (HCRES) and its sodium salt (NaCRES) were determined by the application of the Pitzer ion-interaction treatment to the solutions neglecting high order terms. The reported values of partial molar volume of 4-methylphenol are in good agreement with literature data.
Registro:
| Documento: | Artículo |
| Título: | Volumetric properties of (4-methylphenol + NaOH) at high temperatures |
| Autor: | Kukuljan, J.A.; Méndez De Leo, L.P.; Alvarez, J.L.; Bianchi, H.L.; Fernández-Prini, R.J. |
| Filiación: | Unidad de Actividad Química, Comision Nacional de Energia Atomica, Av. Libertador 8250, 1429, Capital Federal, Argentina Escuela de Ciencia y Tecnologia, Univ. Nac. General San Martín, Alem 3901, 1651, San Andrés, Argentina Universidad Tecnologica Nacional, Facultad Regional Bs. As, Medrano 951, 1179, Bs.As., Argentina Inst. de Quimica Fis. de Materiales, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon II, 1428, Capital Federal, Argentina |
| Palabras clave: | 4-Methylphenol; Densities; Equilibrium association constant; Partial molar volume; Sodium salt of 4-methylphenol; Density (specific gravity); Phase equilibria; Phenols; Sodium compounds; Volume fraction; Equilibrium association constant; Partial molar volume; Thermodynamics |
| Año: | 2003 |
| Volumen: | 35 |
| Número: | 9 |
| Página de inicio: | 1541 |
| Página de fin: | 1552 |
| DOI: | http://dx.doi.org/10.1016/S0021-9614(03)00131-9 |
| Título revista: | Journal of Chemical Thermodynamics |
| Título revista abreviado: | J Chem Thermodyn |
| ISSN: | 00219614 |
| CODEN: | JCTDA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219614_v35_n9_p1541_Kukuljan |
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Citas:
---------- APA ----------
Kukuljan, J.A., Méndez De Leo, L.P., Alvarez, J.L., Bianchi, H.L. & Fernández-Prini, R.J. (2003) . Volumetric properties of (4-methylphenol + NaOH) at high temperatures. Journal of Chemical Thermodynamics, 35(9), 1541-1552.http://dx.doi.org/10.1016/S0021-9614(03)00131-9
---------- CHICAGO ----------
Kukuljan, J.A., Méndez De Leo, L.P., Alvarez, J.L., Bianchi, H.L., Fernández-Prini, R.J. "Volumetric properties of (4-methylphenol + NaOH) at high temperatures" . Journal of Chemical Thermodynamics 35, no. 9 (2003) : 1541-1552.http://dx.doi.org/10.1016/S0021-9614(03)00131-9
---------- MLA ----------
Kukuljan, J.A., Méndez De Leo, L.P., Alvarez, J.L., Bianchi, H.L., Fernández-Prini, R.J. "Volumetric properties of (4-methylphenol + NaOH) at high temperatures" . Journal of Chemical Thermodynamics, vol. 35, no. 9, 2003, pp. 1541-1552.http://dx.doi.org/10.1016/S0021-9614(03)00131-9
---------- VANCOUVER ----------
Kukuljan, J.A., Méndez De Leo, L.P., Alvarez, J.L., Bianchi, H.L., Fernández-Prini, R.J. Volumetric properties of (4-methylphenol + NaOH) at high temperatures. J Chem Thermodyn. 2003;35(9):1541-1552.http://dx.doi.org/10.1016/S0021-9614(03)00131-9
